| Identification | Back Directory | [Name]
(+)-Ipc2B(allyl), 1M in dioxane | [CAS]
106356-53-0 | [Synonyms]
(+)-Ipc2B(allyl), 1M in dioxane
(+)-IPC2B(ALLYL), 1M IN PENTANE
(+)-Ipc2B(allyl)borane solution
(+)-Ipc2B(allyl)borane solution 1 M in pentane
Borane, 2-propen-1-ylbis[(1S,2R,3S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl]- | [Molecular Formula]
C23H39B | [MDL Number]
MFCD09038447 | [MOL File]
106356-53-0.mol | [Molecular Weight]
326.37 |
| Chemical Properties | Back Directory | [Boiling point ]
35-36 °C | [density ]
0.735 g/mL at 25 °C | [Fp ]
12 °C | [storage temp. ]
-20°C | [Optical Rotation]
[α]20/D +14°, c = 1 in pentane | [InChI]
1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m0/s1 | [InChIKey]
ZIXZBDJFGUIKJS-AXSQLCHVSA-N | [SMILES]
C[C@@H]1[C@H](C[C@H]2C[C@@H]1C2(C)C)B(CC=C)[C@H]3C[C@H]4C[C@@H]([C@@H]3C)C4(C)C |
| Hazard Information | Back Directory | [Uses]
This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols. | [General Description]
http://www.sigmaaldrich.com/ifb/acta/v35/acta-vol35-2002.html#32 |
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