ChemicalBook--->CAS DataBase List--->1070-71-9

1070-71-9

1070-71-9 Structure

1070-71-9 Structure
IdentificationBack Directory
[Name]

Cyanoacetylene
[CAS]

1070-71-9
[Synonyms]

cyanoethyne
1-Cyanoethyne
cyanaethylene
Cyanoacetylene
Propynenitrile
PROPIOLONITRILE
Ethynyl cyanide
prop-2-ynenitrile
Acetylenecarbonitrile
2-Propynenitrile (9CI)
Propynenitrile DISCONTINUED
[Molecular Formula]

C3HN
[MDL Number]

MFCD01696133
[MOL File]

1070-71-9.mol
[Molecular Weight]

51.05
Chemical PropertiesBack Directory
[Melting point ]

5℃
[Boiling point ]

42.5℃
[density ]

0.8159 g/cm3 (17 ºC)
[refractive index ]

1.40072 (17℃)
[Fp ]

-30.5±12.6℃
[solubility ]

sol benzene, EtOH, acetonitrile, cyclohexane, toluene, ether.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Skull and Crossbones (GHS06)
GHS02,GHS06
[Signal word ]

Danger
[Hazard statements ]

H330-H300-H310-H225
[Precautionary statements ]

P262-P264-P270-P280-P302+P350-P310-P322-P361-P363-P405-P501-P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378-P403+P235-P501-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P264-P270-P301+P310-P321-P330-P405-P501
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1,3,5-Hexatriyne-->4H-Pyran-3,5-dicarbonitrile, 2-amino-4-phenyl--->but-2-ynedinitrile-->ethene-->HYDROGEN CYANIDE-->ACETYLENEDICARBOXAMIDE-->5-CYANO-2H-PYRAN-2-ONE-->TRIBUTYLSTANNYLACETYLENE
[Preparation Products]

Diacetylene-->1-BUTEN-3-YNE-->Cyanoacetylene-->3,3-Diethoxypropionitrile
Hazard InformationBack Directory
[Chemical Properties]

Liquid. Melting point 5°C, boiling point 42.5°C, relative density 0.8167 (17/4°C), refractive index 1.3868. Soluble in ethanol but poorly soluble in water. Decomposes readily when exposed to air and light.
[Uses]

2-Propynenitrile, is the simplest cyanopolyyne. It has been detected by spectroscopic methods in interstellar clouds, in the coma of comet Hale–Bopp and in the atmosphere of Saturn''s moon Titan, where it sometimes forms expansive fog-like clouds.
[Application]

Cyanoacetylene can be used for nucleophilic conjugate additions to (Z)-olefins; Diels-Alder reactions, and dipolar cycloadditions with nitrones and diazo compounds.
[Preparation]

Cyanoacetylene is not commercially available, but can be prepared on a several gram scale by the dehydration of  propynamide (propiolamide) with Phosphorus(V) Oxide (eq 1). The reactants are well ground together under nitrogen, and  upon subjection of the resulting solid mixture to high temperature treatment, propynenitrile is collected as a distillate in a  receiver held at 5 °C.
Cyanoacetylene
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