| Identification | Back Directory | [Name]
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V) | [CAS]
108695-90-5 | [Synonyms]
OXOTRICHLORO(DIMETHYLSULFIDE)TRIPHENYLPHOSPHINE OXIDE)RHENIUM(V)
Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium
(OC-6-21)-Trichlorooxo[thiobis[methane]](triphenylphosphine oxide-κO)rhenium | [Molecular Formula]
C20H22Cl3O2PReS | [MDL Number]
MFCD08276862 | [MOL File]
108695-90-5.mol | [Molecular Weight]
649.98 |
| Chemical Properties | Back Directory | [form ]
powder | [InChI]
1S/C18H15OP.C2H6S.3ClH.O.Re/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-2;;;;;/h1-15H;1-2H3;3*1H;;/q;;;;;;+3/p-3 | [InChIKey]
GIBDGLAUIKUJJX-UHFFFAOYSA-K | [SMILES]
CSC.Cl[Re](Cl)(Cl)=O.O=P(c1ccccc1)(c2ccccc2)c3ccccc3 |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Enantioselective reduction of ketones and imines
- Meyer-Schuster rearrangement of propargylic alcohols to α, β-unsaturated carbonyl compounds
- Synthesis of 2-deoxy-α glycosides
- Sulfurization of phosphorous(III) compounds with thiiranes
Reactant for synthesis of mono and dinuclear compounds
Reagent for rhenium-cyclized somatostatine derivative series synthesis | [reaction suitability]
core: rhenium
reagent type: catalyst |
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