| Identification | Back Directory | [Name]
TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE | [CAS]
109704-53-2 | [Synonyms]
triacetoxyboranuide
Tetramethyltriammonium
TETRAMETHYLAMMONIUM TRIACETOXYBOROHYDRIDE
Tetramethylammonium triacetoxyborohydride 95%
Tetramethylammonium Triacetoxyborohydride (>
TetraMethylaMMoniuM triacetoxyborohydride, 90+% | [Molecular Formula]
C10H22BNO6 | [MDL Number]
MFCD00012196 | [MOL File]
109704-53-2.mol | [Molecular Weight]
263.1 |
| Chemical Properties | Back Directory | [Melting point ]
93-98 °C(lit.)
| [storage temp. ]
2-8°C
| [solubility ]
slightly sol. in dichloromethane | [form ]
powder to crystal | [color ]
White to Almost white | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [BRN ]
8238791 | [InChI]
1S/C6H10BO6.C4H12N/c1-4(8)11-7(12-5(2)9)13-6(3)10;1-5(2,3)4/h7H,1-3H3;1-4H3/q-1;+1 | [InChIKey]
LCFZZOGKVOTFPU-UHFFFAOYSA-N | [SMILES]
C[N+](C)(C)C.CC(=O)O[BH-](OC(C)=O)OC(C)=O |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
15-36/37/38 | [Safety Statements ]
26-36-43 | [RIDADR ]
UN 2813 4.3/PG 2
| [WGK Germany ]
3
| [F ]
3-10-21 | [HazardClass ]
4.3 | [PackingGroup ]
III | [HS Code ]
29239000 | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Water-react 2 |
| Hazard Information | Back Directory | [Uses]
Selective reducing agent. | [reaction suitability]
reagent type: reductant | [Synthesis]
Tetramethylammonium Triacetoxyborohydride is synthesized by:
| [storage]
Tetramethylammonium triacetoxyborohydride is moisture sensitive; irritant. Stable at 25 °C. Handle in a well ventilated fume hood.
| [Purification Methods]
If impure, wash it with freshly distilled Et2O and dry it overnight in a vacuum to give a free flowing powder. Check 1H NMR, and if still suspect prepare it freshly from Me4NBH4 and AcOH in *C6H6 and store it away from moisture [Banus et al. J Am Chem Soc 74 2346 1952, Evans & Chipman Tetrahedron Lett 27 5939 1986]. Itisan IRRITANT and MOISTURE SENSITIVE. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|