| Identification | Back Directory | [Name]
SPPO1 , 9,9-spirobifluoren-2-yl-diphenyl-phosphine oxide | [CAS]
1125547-88-7 | [Synonyms]
SPPO1
9,9-spirobifluoren-2-yl-diphenyl-phosphine oxide
9,9'-Spirobi[fluoren]-7-yldiphenylphosphine oxide
9,9'-Spirobi[fluoren]-2-yldiphenylphosphine oxide
Diphenyl-9,9'-spirobi[9H-fluoren]-2-ylphosphine oxide
SPPO1 , 9,9-spirobifluoren-2-yl-diphenyl-phosphine oxide
Phosphine oxide, diphenyl-9,9'-spirobi[9H-fluoren]-2-yl-
Diphenyl[9,9'-spirobi[9H-fluoren]-2-yl]phosphine Oxide (This product is only available in Japan.) | [Molecular Formula]
C37H25OP | [MDL Number]
MFCD27978273 | [MOL File]
1125547-88-7.mol | [Molecular Weight]
516.57 |
| Chemical Properties | Back Directory | [Melting point ]
236℃ | [Boiling point ]
719.6±60.0 °C(Predicted) | [density ]
1.32±0.1 g/cm3(Predicted) | [form ]
powder/crystals | [color ]
White | [InChI]
1S/C37H25OP/c38-39(26-13-3-1-4-14-26,27-15-5-2-6-16-27)28-23-24-32-31-19-9-12-22-35(31)37(36(32)25-28)33-20-10-7-17-29(33)30-18-8-11-21-34(30)37/h1-25H | [InChIKey]
DJCKLSMZHDXGHG-UHFFFAOYSA-N | [SMILES]
O=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC4=C(C=C3)C5=C(C=CC=C5)C64C(C=CC=C7)=C7C8=C6C=CC=C8 | [Absorption]
λmax 317 nm (dichloromethane) | [Photoluminescence]
λem 347 nm (dichloromethane) |
| Hazard Information | Back Directory | [Description]
SPPO1, 9,9-Spirobifluoren-2-yl-diphenyl-phosphine oxide has a spirobifluorene structure with an electron deficient polar diphenyl-phosphine oxide moiety attached. The polarity in the P=O double bond can lead to a high triplet energy state, which is highly desirable in host materials for an efficient host-to guest energy transfer in an OLED. |
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| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
3A Chemicals
|
| Telephone: |
400-668-9898 |
| Website: |
www.3achem.com |
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