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113939-45-0

113939-45-0 Structure

113939-45-0 Structure
IdentificationBack Directory
[Name]

1-bromo-4-(2-bromo-1,1,2,2-tetrafluoroethoxy)benzene
[CAS]

113939-45-0
[Synonyms]

Thiazole,2-bromo-8-methyl-
1-bromo-4-(2-bromo-1,1,2,2-tetrafluoroethoxy)benzene
Benzene, 1-bromo-4-(2-bromo-1,1,2,2-tetrafluoroethoxy)-
[Molecular Formula]

C8H4Br2F4O
[MDL Number]

MFCD31546217
[MOL File]

113939-45-0.mol
[Molecular Weight]

351.92
Chemical PropertiesBack Directory
[Boiling point ]

238.6±40.0 °C(Predicted)
[density ]

1.942±0.06 g/cm3(Predicted)
[form ]

liquid
[InChI]

1S/C8H4Br2F4O/c9-5-1-3-6(4-2-5)15-8(13,14)7(10,11)12/h1-4H
[InChIKey]

MHPXJSIMKFXETB-UHFFFAOYSA-N
[SMILES]

FC(F)(Br)C(F)(F)Oc1ccc(cc1)Br
Safety DataBack Directory
[WGK Germany ]

WGK 3
[Storage Class]

10 - Combustible liquids
Hazard InformationBack Directory
[Uses]

4-Bromophenoxytetrafluoroethyl bromide is a fluoroalkylbromide that is a radical source of the 4-bromophenoxytetrafluoroethyl moiety. Alternatively, it can also be selectively metallated at the fluorinated carbon with Turbo Grignard reagent at low temperatures resulting in a thermally unstable anion that can act as a nucleophilic fluoroalkylation reagent towards a wide variety of electrophiles, such as aldehydes, ketones or sulfonylimines.The aromatic bromide can be further subjected to Pd-catalyzed cross-coupling reactions to build molecular complexity.
[reaction suitability]

reaction type: C-C Bond Formation
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