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118089-84-2

118089-84-2 Structure

118089-84-2 Structure
IdentificationBack Directory
[Name]

N-BENZYLCINCHONIDINIUM BROMIDE
[CAS]

118089-84-2
[Synonyms]

N-BENZYLCINCHONIDINIUM BROMIDE
N-Benzylcinchonidinium bromide 97%
[Molecular Formula]

C26H29BrN2O
[MDL Number]

MFCD06799030
[MOL File]

118089-84-2.mol
[Molecular Weight]

465.43
Chemical PropertiesBack Directory
[Melting point ]

190 °C (dec.)(lit.)
[Optical Rotation]

[α]20/D 138°, c = 1 in chloroform
[InChIKey]

UUVFTQCFSNVLGV-SPTWEYDNSA-M
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

N-Benzylcinchonidinium bromide (BCDBr) can be used:
  • To prepare various 4-(bromomethyl)benzenesulfonamides, which are employed as catalysts for asymmetric benzylation reactions.
  • As a phase transfer catalyst in the synthesis of organogelators via Michael addition reaction.
  • To catalyze the enantioselective alkylation of tert-butyl glycinate-benzophenone Schiff base furnishing the corresponding chiral α-amino acid.
  • To resolve symmetric biaryldiols via formation of inclusion complex with diols.

[General Description]

N-Benzylcinchonidinium bromide is a chiral phase-transfer catalyst (PTC).
Spectrum DetailBack Directory
[Spectrum Detail]

N-BENZYLCINCHONIDINIUM BROMIDE(118089-84-2)IR
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