Identification | Back Directory | [Name]
(S)-2-(Methoxydiphenylmethyl)pyrrolidine | [CAS]
118971-03-2 | [Synonyms]
-2-(Methoxydiphenylmethyl) (S)-2-(Methoxydiphenylmethyl)pyrrolidine (2S)-2-(Methoxydiphenylmethyl)pyrrolidine (2S)-2-[Diphenyl(methoxy)methyl]pyrrolidine Pyrrolidine, 2-(methoxydiphenylmethyl)-, (2S)- (2S)-2-[Diphenyl(methoxy)methyl]tetrahydropyrrole (S)-2-(MethoxydiphenylMethyl)pyrrolidine 95% (HPLC) | [Molecular Formula]
C18H21NO | [MDL Number]
MFCD09750440 | [MOL File]
118971-03-2.mol | [Molecular Weight]
267.37 |
Chemical Properties | Back Directory | [Boiling point ]
368.7±32.0 °C(Predicted) | [density ]
1.070±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C | [solubility ]
soluble in Dichloromethane, Ethyl Acetate | [form ]
Oil | [pka]
10.09±0.10(Predicted) | [color ]
Yellow |
Hazard Information | Back Directory | [Uses]
(S)-2-(Methoxydiphenylmethyl)pyrrolidine is a diphenylprolinol methyl ether, which can be used as a catalyst to synthesize:
- Enantioselective ketones via intermolecular asymmetric Michael addition of aldehydes to nonactivated enones.
- Stereoselective chiral bipyrazolidin-3-one derivatives by dipolar cycloaddition reaction of azomethine imines with α, β-unsaturated aldehydes.
- Enantioenriched spiro nitrogen heterocycles via asymmetric nucleophilic epoxidation of α-ylideneoxindole esters.
- Optically active secondary alcohols by asymmetric addition of Et2Zn to various aldehydes.
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NovoChemy Ltd.
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SynAsst Chemical.
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