ChemicalBook--->CAS DataBase List--->12018-10-9

12018-10-9

12018-10-9 Structure

12018-10-9 Structure
IdentificationBack Directory
[Name]

Copper chromite
[CAS]

12018-10-9
[Synonyms]

CUPRICCHROMITE
COPPER CHROMITE
COPPER(II) CHROMITE
chromium copper oxid
COPPERCHROMIUM OXIDE
COPPER(II)CHROMATE(III)
COPPER CHROMITE CATALYST
tetraoxid dichromito-me?naty
chromiumcopperoxide(cr2cuo4)
copper dichromium tetraoxide
COPPER(II)DICHROMATE,DIHYDRATE
CopperchromitebariumpromotedCrCuOCuOBaO
62-64%Cr2CuO4,22-24%CuO,6%BaO,0-4%graphite1%CrO31%Cr2O3CrO31%Cr2O3
Copperchromite,bariumpromoted(62-64%Cr2CuO4,22-24%CuO,6%BaO,0-4%Graphite,1%CrO3,1%Cr2O3)
[EINECS(EC#)]

235-000-1
[Molecular Formula]

CrCuO3
[MDL Number]

MFCD00044868
[MOL File]

12018-10-9.mol
[Molecular Weight]

163.54
Chemical PropertiesBack Directory
[Appearance]

fine brown to black powder
[density ]

5.400
[vapor pressure ]

0-0.08Pa at 190-200℃
[solubility ]

insoluble in H2O, dilute acid solutions
[form ]

Powder
[color ]

Brown to black
[Water Solubility ]

insoluble H2O, dilute acids, conc HCl [MER06]
[InChI]

InChI=1S/2Cr.Cu.4O
[InChIKey]

FULFYAFFAGNFJM-UHFFFAOYSA-N
[SMILES]

O([Cr]=O)[Cr]=O.O=[Cu]
[EPA Substance Registry System]

Chromium copper oxide (Cr2CuO4)(12018-10-9)
Hazard InformationBack Directory
[Chemical Properties]

fine brown to black powder
[Physical properties]

Grayish-black tetragonal crystals; density 5.4 g/cm3. When heated to elevated temperatures (above 900°C) copper(II) chromite decomposes to cupric chromate(II), CuCrO2 and chromium (VI) oxide, CrO3. Copper(II) chromite is insoluble in water and dilute acids.
[Uses]

Copper chromite is used as a hydrogenation catalyst.
[Application]

Copper chromite is primarily used as a catalyst forhydrogenation reactions because of its ability to hydrogenate functional groupsin aliphatic and aromatic compounds selectively. Industrially, copper chromiteis used to reduce furfural to furfuryl alcohol and butyraldehyde to 1-butanol,partially reduce conjugated dienes to monoenes, and selectively reduce carbonylgroups in vegetable oils. This CuCr catalyst is studied for a variety ofcatalytic applications including converting the hydrogenolysis of cellulose.It is also used as a catalyst for combustion to help control burn rate and as alight-absorbing pigment.
[Preparation]

Copper(II) chromite is obtained by heating copper chromate, CuCrO4 at 400°C. The Adkin catalyst, a mixture of copper oxide and copper chromite, is prepared by mixing aqueous solutions of copper nitrate, sodium dichromate and ammonium hydroxide; the orange precipitate of copper ammonium chromate formed is dried and then heated below 400°C.
[General Description]

Copper chromite is a black powder and inorganic pigment thatadopts a spinel crystal structure. It can be made by the high-temperaturecalcination of copper(II) oxide and chromium(III) oxide or the thermaldecomposition of copper chromate, which evolves oxygen at higher temperaturesand decomposes to copper chromite.
Safety DataBack Directory
[Hazard Codes ]

O,Xi
[Risk Statements ]

8-37-36/37/38-20/21
[Safety Statements ]

17-24/25-23
[RIDADR ]

UN 1479 5.1/PG 2
[WGK Germany ]

3
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

28415000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium dichromate
[Preparation Products]

2-Butanone-->1,6-Hexanediol-->XW101 catalyst for nitric acid exhaust purification
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Copper chromite (12018-10-9).msds
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