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12046-08-1

12046-08-1 Structure

12046-08-1 Structure
IdentificationBack Directory
[Name]

BARIUM HEXABORIDE
[CAS]

12046-08-1
[Synonyms]

BARIUM BORIDE
BARIUM HEXABORIDE
(oc-6-11)-bariumboride(bab6
BARIUM HEXABORIDE -100 MESH
BariumHexaboride(MetalsBasis)
BARIUM HEXABORIDE ISO 9001:2015 REACH
BARIUM HEXABORIDE, 99.5% (METALS BASIS)
[EINECS(EC#)]

234-965-6
[Molecular Formula]

B6BaH4
[MDL Number]

MFCD00191767
[MOL File]

12046-08-1.mol
[Molecular Weight]

206.22
Chemical PropertiesBack Directory
[Melting point ]

2270°C
[density ]

4.36 g/mL at 25 °C(lit.)
[solubility ]

insoluble in H2O; soluble in acid solutions; insoluble in EtOH
[form ]

black cubic crystals
[color ]

black cubic crystals, crystalline
[Water Solubility ]

Soluble in HNO<sub>3</sub>. Insoluble in water
[Thermal Conductivity]

44.769 W/(m·K)
[EPA Substance Registry System]

Barium boride (BaB6), (OC-6-11)- (12046-08-1)
Hazard InformationBack Directory
[Chemical Properties]

metallic black cub; -100 mesh 99.5% purity [CER91] [CRC10]
[Uses]

Barium hexaboride has been considered as a candidate for manufacture of a “hot-cathode” electron gun for use in various instruments.
[Preparation]

Barium boride can be formed directly from the elements. Ba melts at 727 °C and boron melts at 2076 °C. Therefore, if a vapor of Ba metal at >750 °C (red-heat) is passed over crystals of boron, a chemical reaction forms the desired boride. However, to obtain stoichiometric compositions, it is better to heat the well-mixed powders of Ba and B to obtain specific compounds:
Ba + 6B→BaB6
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/22
[Safety Statements ]

28
[RIDADR ]

UN 1564 6.1/PG 2
[WGK Germany ]

1
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
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