ChemicalBook--->CAS DataBase List--->12079-65-1

12079-65-1

12079-65-1 Structure

12079-65-1 Structure
IdentificationBack Directory
[Name]

CYCLOPENTADIENYLMANGANESE TRICARBONYL
[CAS]

12079-65-1
[Synonyms]

Cymantrene
Cyklopentadientrikarbonylmanganium
MAGANESECYCLOPENTADIENYLTRICARBONYL
Manganese tricarbonylcyclopentadiene
CYCLOPENTADIENYLTRICARBONYLMANGANESE
manganesecyclopentadienyltricarbonyl
Tricarbonylcyclopentadienylmanganese
manganese,cyclopentadienyltricarbonyl
CYCLOPENTADIENYLMANGANESE TRICARBONYL
Cyclopentadiene Manganese Tricarbonyl
Cyclopentadienyl marganese tricarbonyl
p-Cyclopentadienylmanganesetricarbonyl
Manganese, cyclopentadienyltricarbonyl-
Cyclopentadienyl-p-tricarbonylmanganese
η5-Cyclopentadienylmanganesetricarbonyl
Cyclopentadienylmanganesetricarbonyl,98%
cyclopentadienylmanganese(i) tricarbonyl
pi-Cyclopentadienylmanganese tricarbonyl
tricarbonyl-pi-cyclopentadienyl-manganes
Tricarbonyl-pi-cyclopentadienylmanganese
Manganese,tricarbonyl-p-cyclopentadienyl-
MANGANESECYCLOPENTADIENYLTRICARBONYL,ASMN
tricarbonyl(eta-cyclopentadienyl)manganese
Manganese, tricarbonyl-pi-cyclopentadienyl-
Tricarbonyl(η5-2,4-cyclopentadien-1-yl)manganese
CyclopentadienylManganese tricarbonyl CyMantrene
tricarbonyl(η5-2,4-cyclopentadien-1-yl)-Manganese
tricarbonyl(eta5-2,4-cyclopentadien-1-yl)-manganes
Manganese,tricarbonyl(η5-2,4-cyclopentadien-1-yl)-
Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)-
Manganese, tricarbonyl(.eta.5-2,4-cyclopentadien-1-yl)-
(eta5-Cyclopentadienyl) manganese tricarbonyl
[EINECS(EC#)]

235-142-4
[Molecular Formula]

C8H5MnO3 5*
[MDL Number]

MFCD00001440
[MOL File]

12079-65-1.mol
[Molecular Weight]

204.06
Chemical PropertiesBack Directory
[Appearance]

yellow crystals or crystalline chunks
[Melting point ]

72-76 °C(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

crystal
[color ]

yellow
[Water Solubility ]

Soluble in water (70 ppm (25C)
[Sensitive ]

Air Sensitive
[Exposure limits]

ACGIH: TWA 0.1 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.1 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
[InChI]

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;
[InChIKey]

CZPHEHHRMHXAIK-UHFFFAOYSA-N
[SMILES]

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1
[Uses]

Antiknock agent.
[EPA Substance Registry System]

Manganese cyclopentadienyl tricarbonyl (12079-65-1)
Hazard InformationBack Directory
[Chemical Properties]

yellow crystals or crystalline chunks
[General Description]

Bright yellow, crystalline solid with a camphor-like odor. Sublimes 75-77°C. Slightly soluble in water. Used as an octane enhancement additive for unleaded gasoline.
[Reactivity Profile]

MANGANESE CYCLOPENTAHIENYL TRICARBONYL is combustible. Heating causes evolution of carbon monoxide and other toxic or irritating gases. Heating in a confined space causes a rise in pressure with the risk of bursting. Incompatible with oxygen.
[Hazard]

Toxic material absorbed by skin. Central nervous system impairment and skin irritant.
[Health Hazard]

Manganese cyclopentadienyl tricarbonyl (MCT) causes convulsions and pulmonary edema in laboratory animals.
[reaction suitability]

core: manganese
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

T+
[Risk Statements ]

28
[Safety Statements ]

28-36/37-45
[OEB]

D
[OEL]

TWA: 0.1 mg/m3 [skin]
[RIDADR ]

UN 2811 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

OO9720000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29310099
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 2 Oral
[Safety Profile]

A poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
[Hazardous Substances Data]

12079-65-1(Hazardous Substances Data)
[Toxicity]

mouse,LD50,intravenous,710ug/kg (0.71mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11285,
Spectrum DetailBack Directory
[Spectrum Detail]

CYCLOPENTADIENYLMANGANESE TRICARBONYL(12079-65-1)1HNMR
CYCLOPENTADIENYLMANGANESE TRICARBONYL(12079-65-1)FT-IR
CYCLOPENTADIENYLMANGANESE TRICARBONYL(12079-65-1)Raman
CYCLOPENTADIENYLMANGANESE TRICARBONYL(12079-65-1)IR
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