| Identification | Back Directory | [Name]
Ferrocenecarboxaldehyde | [CAS]
12093-10-6 | [Synonyms]
formyl-ferrocen
FORMYLFERROCENE
FERROCENEALDEHYDE
Ferrocene, formyl-
Ferrocenecarboxaldeh
FERROCENECARBALDEHYDE
FERROCENECARBOXALDEHYDE
Ferrocene Carboxyaldehyde
Ferrocenecarboxaldehyde 98%
Ferrocenecarboxaldehyde,98%
Ferrocenecarboxaldehyde,min.98%
Ferrocenecarboxaldehyde, 98% 5GR
Ferrocene carboxaldehyde, min. 98%
CYCLOPENTADIENYL(FORMYL-CYCLOPENTADIENYL)IRON
Ferrocenecarboxaldehyde,Cyclopentadienyl(formylcyclopentadienyl)iron
Ferrocenecarboxaldehyde SynonyMs Cyclopentadienyl(forMylcyclopentadienyl)iron | [EINECS(EC#)]
235-158-1 | [Molecular Formula]
C11H10FeO 10* | [MDL Number]
MFCD00001429 | [MOL File]
12093-10-6.mol | [Molecular Weight]
214.04 |
| Chemical Properties | Back Directory | [Appearance]
crystalline solid | [Melting point ]
118-120 °C(lit.)
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
Crystalline Powder or Crystals or Crystals | [color ]
Orange to red to brown | [Stability:]
Stable. Incompatible with strong oxidizing agents. | [Water Solubility ]
INSOLUBLE | [Sensitive ]
Air Sensitive | [λmax]
314nm(DMF aq.)(lit.) | [Exposure limits]
ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3 | [InChI]
InChI=1S/C6H5O.C5H5.Fe/c7-5-6-3-1-2-4-6;1-2-4-5-3-1;/h1-5H;1-5H; | [InChIKey]
UQTCQJVPLIVCAX-UHFFFAOYSA-N | [SMILES]
[C]1(C=O)[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Fe] |^1:0,3,4,5,6,7,8,9,10,11| | [EPA Substance Registry System]
Ferrocene, formyl-(12093-10-6) |
| Hazard Information | Back Directory | [Chemical Properties]
crystalline solid | [Uses]
Ferrocenecarboxaldehyde, is used to prepare chiral ferrocene aziridinylmethanols for selective azomethine ylide cycloaddtion. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals. | [reaction suitability]
core: iron
reagent type: catalyst | [Purification Methods]
It forms red crystals from heptane/CH2Cl2, EtOH or pet ether and sublimes at 70o/1mm. The cyanohydrin has m 104o (from *C6H6/EtOH). The semicarbazone has m 217-219o(dec) after recrystallisation from aqueous EtOH. The oxime provides two isomers from pet ether viz m 96-99o and m 155o. The O-acetyloxime has m 80-81o after recrystallisation from hexane [Lindsay & Hauser J Org Chem 22 355 1957]. The 2,4-dinitrophenylhydrazone has m 248o(dec). [Beilstein 16 IV 1798, Graham et al. J Am Chem Soc 79 3416 1957, Broadhead et al. J Chem Soc 650 1958.] |
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