| Identification | Back Directory | [Name]
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) | [CAS]
12120-15-9 | [Synonyms]
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
Ethylenebis(triphenylphosphine)Platinum(II)
bis(triphenylphosphine)(ethylene)platinum(0)
Ethylenebis(triphenylphosphine)platinum(0),98% | [Molecular Formula]
C38H34P2Pt | [MDL Number]
MFCD00012028 | [MOL File]
12120-15-9.mol | [Molecular Weight]
747.7 |
| Chemical Properties | Back Directory | [Appearance]
light yellow to beige powder | [Melting point ]
127-131 °C
| [storage temp. ]
Refrigerator (+4°C) | [solubility ]
sol benzene, THF, dichloromethane; insol alcohols | [InChI]
1S/2C18H15P.C2H4.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h2*1-15H;1-2H2; | [InChIKey]
RZUASTIKPBCXPU-UHFFFAOYSA-N | [SMILES]
[Pt].C=C.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6 |
| Hazard Information | Back Directory | [Chemical Properties]
light yellow to beige powder | [Uses]
Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds | [Preparation]
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be prepared by the reduction of [Pt(PPh3)2(CO)3)]. PhH with Sodium Borohydride in ethylene saturated EtOH. | [reaction suitability]
core: platinum
reagent type: catalyst | [storage]
ETHYLENEBIS(TRIPHENYLPHOSPHINE)PLATINUM(0) can be briefly handled in air and stored indefinitely under nitrogen. |
|
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