| Identification | Back Directory | [Name]
BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE | [CAS]
121309-88-4 | [Synonyms]
Benzyltrimethylaminium
Trimethylbenzylaminium
chlorinatingreagent]95+%
Dimethyl(benzyl)(methyl)aminium
N,N,N-Trimethylbenzenemethanaminium
Benzyltrimethylammonium trichloroiodide
BENZYLTRIMETHYLAMMONIUM &
BENZYLTRIMETHYLAMMONIUM TETRACHLOROIODATE
N-Benzyl-N,N,N-trimethylammonium tetrachloroiodate
Benzyltrimethylammonium tetrachloroiodate purum, >=98.0% (AT)
Benzyltrimethylammonium Tetrachloroiodate [Chlorinating Reagent]
Benzyltrimethylammonium Tetrachloroiodate [Chlorinating Reagent]> | [Molecular Formula]
C10H16Cl4IN | [MDL Number]
MFCD00191607 | [MOL File]
121309-88-4.mol | [Molecular Weight]
418.96 |
| Chemical Properties | Back Directory | [Melting point ]
106-125 °C | [solubility ]
sol MeCN, MeNO3, DMSO, DMF; slightly sol MeOH, EtOH, AcOH, AcOEt, CHCl3, CH2Cl2; insol C6H14, CCl4, C6H6, H2O. | [form ]
powder to crystal | [color ]
Light yellow to Brown | [BRN ]
4619219 | [CAS DataBase Reference]
121309-88-4 |
| Hazard Information | Back Directory | [Uses]
Benzyltrimethylammonium tetrachloroiodate is a chlorinating agent for aromatic compounds; it can be used for side chain chlorination of aromatic compounds and chlorine addition of olefins. | [Preparation]
Chlorine gas was passed into a solution of benzyltrimethylammonium chloride (18.6 g, 0.1 mol) and iodine (12.7 g, 0.05 mol) in CH2Cl2 (300 mL) for 15 min; the yield of BEnzyltrimethylammonium tetrachloroiodate was 40 g (95%). | [storage]
Stable solid, but gradually decomposes with evolution of Cl2 when in contact with air for a long time. This reagent should be handled in a fume hood. |
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Sigma-Aldrich
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