| Identification | Back Directory | [Name]
Chlorobis(cyclooctene)rhodium(I) dimer | [CAS]
12279-09-3 | [Synonyms]
[Rh(coe)2Cl]2
Chlorobis(cyclooctene)rhodium(I)
CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
Chlorobis(cyclooctene)rhodium(I)dimere
CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER
Chlorobis(cyclooctene)rhodiuM(I),diMer 98%
Chlorobis(cyclooctene)rhodium(I) dimer,98%
Chlorobis(cyclooctene)rhodium(I)dimer,min.98%
Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%
Chlorobis(cyclooctene)rhodiuM(I) diMer, 98% 100MG | [EINECS(EC#)]
623-340-7 | [Molecular Formula]
C32H56Cl2Rh2 | [MDL Number]
MFCD00013287 | [MOL File]
12279-09-3.mol | [Molecular Weight]
717.5 |
| Chemical Properties | Back Directory | [Appearance]
orange-brown powder | [Melting point ]
190 °C (dec.)(lit.)
| [storage temp. ]
Freezer | [form ]
crystal | [color ]
orange to red | [Optical Rotation]
-0.60°(C=0.01g/ml CHCL3) | [Sensitive ]
air sensitive, store cold | [InChI]
1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;; | [InChIKey]
GQPAPAIPOLEZHT-XFCUKONHSA-L | [SMILES]
Cl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4 | [CAS DataBase Reference]
12279-09-3 |
| Hazard Information | Back Directory | [Chemical Properties]
orange-brown powder | [Uses]
Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
- To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
- In direct C-arylation of N-unprotected indoles and pyrroles.
- In the carboxylation of arenes via C-H bond activation.
| [reaction suitability]
core: rhodium
reagent type: catalyst |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22-36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
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