| Identification | Back Directory | [Name]
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) | [CAS]
12289-94-0 | [Synonyms]
Ru(Me-allyl)2(COD)
Bis(2-methylallyl)
-1,5-cyclooctadieneruthenium (II)
BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&
BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&
Bis(2-methallyl)(1,5-cyclooctadiene)ruthenium
(1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium
(1Z,5Z)-1,2-bis(2-methylallyl)cycloocta-1,5-diene
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(Ⅱ)
BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)RUTHENIUM(II)
Bis(2-Methylallyl)(1,5-cyclooctadiene)rutheniuM(II),97%
bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(ii),min.
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II),min.97%
BIS-(2-METHYLALLYL)CYCLOOCTA-1,5-DIENE RUTHENIUM (II) COMPLEX
RutheniumCyclooctadieneBis(2,2,6,6-Tetramethylheptanedionate)
Ruthenium(II) bis(2-methylallyl) 1,5-cyclooctadiene complex
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru
Bis-(2-Methylallyl)cycloocta-1,5-diene rutheniuM(II) coMplex, 30-32% Ru 250MG
Bis(2-Methylallyl)(1,5-cyclooctadiene)rutheniuM(Ⅱ), 32% Ru, Product of UMicore
RutheniuM, [(1,2,5,6-η)-1,5-cyclooctadiene]bis[(1,2,3-η)-2-Methyl-2-propenyl]-(9CI)
RutheniuM, [(1,2,5,6-h)-1,5-cyclooctadiene]bis[(1,2,3-h)-2-Methyl-2-propenyl]- (9CI) | [Molecular Formula]
C8H14Ru.C8H12 | [MDL Number]
MFCD08273780 | [MOL File]
12289-94-0.mol | [Molecular Weight]
319.45 |
| Chemical Properties | Back Directory | [Appearance]
tan/brown powder | [Melting point ]
81-85 °C
| [Boiling point ]
100°C/0.05mmHg | [storage temp. ]
0-6°C | [form ]
Powder | [color ]
tan to brown | [Water Solubility ]
It is soluble in water. | [Sensitive ]
Air & Moisture Sensitive | [Stability:]
store cold | [InChI]
InChI=1S/C8H8.2C4H5.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H2;2*1-2H,3H3;/q;2*-1;+2 | [InChIKey]
KMYRLYRRLMVJNK-XMWBDPRZSA-N | [SMILES]
CC12=C[Ru+2]345671(C=C3(C)[CH-]4)(C1CCC5=C6CCC7=1)[CH-]2 |
| Hazard Information | Back Directory | [Chemical Properties]
tan/brown powder | [Uses]
| [Uses]
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. | [reaction suitability]
core: ruthenium
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reaction]
- Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
- β-ketoester reduction.
- Anti-Markovnikov addition of amides to alkynes.
- Anti-Markovnikov hydroamination of vinylarenes.
- Catalyst for the addition of amides to alkynes.
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