| Identification | Back Directory | [Name]
ROT 300 | [CAS]
123174-58-3 | [Synonyms]
ROT 300
GC-R2etherate
Fluorescense red
Gc-r2 etherification
N,N'-Bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxyperylene-3,4:9,10-tetracarboxdiimide
N,N'-Bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic Diimide
N,N'-Bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic Diimide >
N,N'-Bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic Diimide
2,9-bis(2,6-diisopropylphenyl)-5,6,12,13-tetraphenoxyanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H,9H)-tetraone | [Molecular Formula]
C72H58N2O8 | [MOL File]
123174-58-3.mol | [Molecular Weight]
1079.24 |
| Chemical Properties | Back Directory | [density ]
1.294±0.06 g/cm3 (20 ºC 760 Torr) | [storage temp. ]
Refrigerator, under inert atmosphere | [solubility ]
DMSO (Slightly), Heptane (Very Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
3.41±0.20(Predicted) | [color ]
Dark Red to Very Dark Brown | [λmax]
577nm(CH2Cl2)(lit.) | [InChIKey]
ZZSIDSMUTXFKNS-UHFFFAOYSA-N |
| Hazard Information | Back Directory | [Chemical Properties]
Red to dark red powder, odorless. Non-flammable or explosive. Fluorescent bright red under 365 nm excitation. Miscible with many petroleum and organic products. | [Uses]
N,N''-Bis(2,6-diisopropylphenyl)-1,6,7,12-tetraphenoxy-3,4,9,10-perylenetetracarboxylic Diimide has applications in the photosensors and optical detectors. | [Synthesis]
Synthesis of bis(2,6-diisopropylphenyl)-5,6,12,13-tetraphenoxyanthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10(2H, 9H)-tetraone(PTCDA): PBI-Cl (1.7 g, 2 mmol) was stirred under argon with phenol (1.6 mL, 16 mmol) in N-methyl-pyrrolidone (60 mL) in a 250 mLround flask in the presence of powdered anhydrous K2CO3 (1.1 g,8 mmol). The temperature was maintained at 90 °C overnight under N2. After cooling to room temperature, the reaction liquid was poured into the water and extracted with ethyl acetate. The combined organic layers were dried over anhydrous Na2SO4 and evaporated in a vacuum. The crude product was purified by chromatography (silica gel, ethylacetate: petroleum=1:10). Red solid ROT 300 was obtained. Yield: 92%。
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