| Identification | Back Directory | [Name]
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole | [CAS]
1239478-87-5 | [Synonyms]
Ad-BGPhos
AdBippyphos
Adamantyl-BippyPhos
5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole
5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-
1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole
1,4'-Bi-1H-pyrazole, 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-1',3',5'-triphenyl-
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole[Adamantyl-BippyPhos
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, (Adamantyl-BippyPhos)
5-[Di(1-adaMantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97+% (AdaMantyl-BippyPhos) | [Molecular Formula]
C44H47N4P | [MDL Number]
MFCD22200502 | [MOL File]
1239478-87-5.mol | [Molecular Weight]
662.84 |
| Chemical Properties | Back Directory | [Melting point ]
295-300°C | [storage temp. ]
2-8°C | [form ]
solid | [pka]
-0.58±0.19(Predicted) | [color ]
white to light yellow | [InChIKey]
IHFBOUNFWVRWAQ-GOSCEEDCSA-N | [SMILES]
C1[C@@H]2C[C@@H]3C[C@H]1C[C@](C2)(C3)P(c4ccnn4-c5c(nn(-c6ccccc6)c5-c7ccccc7)-c8ccccc8)[C@@]9%10C[C@@H]%11C[C@@H](C[C@@H](C%11)C9)C%10 |
| Hazard Information | Back Directory | [Uses]
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole can be used as a catalyst. | [Uses]
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole (Ad-BippyPhos) is an effective ligand that catalyzes C-O coupling reactions of aryl and heteroaryl bromides/chlorides with primary aliphatic alcohols. It can also be used as a catalyst in the synthesis of fluorinated anilines by coupling fluoroalkylamines with aryl bromides and chlorides. | [reaction suitability]
reagent type: ligand |
|
| Company Name: |
Adamas Reagent, Ltd.
|
| Telephone: |
4006009262 13023226327 |
| Website: |
http://www.tansoole.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|