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1242421-77-7

1242421-77-7 Structure

1242421-77-7 Structure
IdentificationBack Directory
[Name]

(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
[CAS]

1242421-77-7
[Synonyms]

(S)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-disulfonimide
(S)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthyl-2,2'-disulfonimide 95%
(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dithiazepine 3,3,5,5-tetraoxide
(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-3,3,5,5-tetraoxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dithiazepine
(11bS)- 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-3,3,5,5-tetraoxide-Dinaphtho[2,1-d:1',2'f][1,3,2]dithiazepine
Dinaphtho[2,1-d:1',2'-f][1,3,2]dithiazepine, 2,6-bis[3,5-bis(trifluoromethyl)phenyl]-, 3,3,5,5-tetraoxide, (11bS)-
[Molecular Formula]

C36H17F12NO4S2
[MDL Number]

MFCD28009151
[MOL File]

1242421-77-7.mol
[Molecular Weight]

819.64
Chemical PropertiesBack Directory
[Melting point ]

325-330°C
[form ]

solid
[InChIKey]

DFXCMPXSCANWFA-UHFFFAOYSA-N
[SMILES]

O=S(C1=C(C2=C(C=CC=C3)C3=CC(C4=CC(C(F)(F)F)=CC(C(F)(F)F)=C4)=C2S5(=O)=O)C6=C(C=CC=C6)C=C1C7=CC(C(F)(F)F)=CC(C(F)(F)F)=C7)(N5)=O
Safety DataBack Directory
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

Chiral Bronsted acid demonstrated in Mukaiyama aldol reactions and Friedel-Crafts alkylation of indoles with sulfonyl imines.

A Powerful Chiral Counteranion Motif for Asymmetric Catalysis

Chiral Sulfonimide as a Br?nsted Acid Organocatalyst for Asymmetric Friedel-Crafts Alkylation of Indoles with Imines

Chiral?N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination
[reaction suitability]

reaction type: Aldol Reaction
reaction type: Allylation
reaction type: Carbonyl/Imine Addition
reaction type: Friedel-Crafts Alkylation
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