| Identification | Back Directory | [Name]
(S)-Ph-quinox >=95% | [CAS]
1252576-13-8 | [Synonyms]
(S)-Ph-quinox
(S)-Ph-quinox >=95%
(S)-4-phenyl-2-(quinolin-2-yl)-4,5-dihydrooxazole
2-[(4S)-4,5-dihydro-4-phenyl-2-
oxazolyl]-Quinoline
Quinoline, 2-[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]- | [Molecular Formula]
C18H14N2O | [MOL File]
1252576-13-8.mol | [Molecular Weight]
274.32 |
| Chemical Properties | Back Directory | [Melting point ]
142°C | [Boiling point ]
476.8±38.0 °C(Predicted) | [density ]
1.22±0.1 g/cm3(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
powder or crystals | [pka]
3.27±0.61(Predicted) |
| Hazard Information | Back Directory | [Uses]
(S)-Ph-quinox is a chiral dinitrogen ligand which is used in the iridium-catalyzed enantioselective borylation and silylation of aromatic C-H bonds, in addition to the enantioselective palladium-catalyzed diamination of alkenes. It can also be used in the aza-Wacker-type cyclization reaction of the olefinic tosylamides with molecular oxygen. | [reaction suitability]
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation |
|
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Rhawn Reagent
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400-400-1332688 18019345275 |
| Website: |
http://www.rhawn.cn |
| Company Name: |
Energy Chemical
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| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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