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1263377-91-8

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1263377-91-8 Structure

1263377-91-8 Structure
IdentificationBack Directory
[Name]

Baran TFPS-Na Reagent
[CAS]

1263377-91-8
[Synonyms]

Baran TFPS-Na Reagent
Sodium trifluoropropylsulfinate
sodium:3,3,3-trifluoropropane-1-sulfinate
3,3,3-trifluoropropane-1-sulfinate Sodium
3,3,3-trifluoropropane-1-sulfinic acid sodium
[Molecular Formula]

C3H6F3NaO2S
[MDL Number]

MFCD18379709
[MOL File]

1263377-91-8.mol
[Molecular Weight]

186.12
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C, stored under nitrogen, away from moisture
[form ]

solid
[Appearance]

White to off-white Solid
[InChI]

1S/C3H5F3O2S.Na/c4-3(5,6)1-2-9(7)8;/h1-2H2,(H,7,8);/q;+1/p-1
[InChIKey]

DVCULODZLVVYHT-UHFFFAOYSA-M
[SMILES]

O=S(CCC(F)(F)F)[O-].[Na+]
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability
[reaction suitability]

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
Spectrum DetailBack Directory
[Spectrum Detail]

Baran TFPS-Na Reagent(1263377-91-8)1HNMR
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