| Identification | Back Directory | [Name]
2-METHYLPROPYLZINC BROMIDE | [CAS]
126403-67-6 | [Synonyms]
ISOBUTYLZINC BROMIDE Isobutylzinc(II) bromide 2-METHYLPROPYLZINC BROMIDE Zinc, bromo(2-methylpropyl)- isobutylzinc bromide solution bromozinc(1+),2-methanidylpropane 2-Methylpropylzinc bromide, 0.5 M in THF Isobutylzinc bromide solution 0.5 in THF Isobutylzinc broMide solution 0.5 M in THF Isobutylzinc broMide, 0.5 M solution in THF, SpcSeal ISOBUTYLZINC BROMIDE, 0.5M SOLUTION IN T ETRAHYDROFURAN Isobutylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles Isobutylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles | [Molecular Formula]
C4H9BrZn | [MDL Number]
MFCD00671802 | [MOL File]
126403-67-6.mol | [Molecular Weight]
202.41 |
| Chemical Properties | Back Directory | [density ]
0.943 g/mL at 25 °C | [Fp ]
1 °F | [storage temp. ]
2-8°C | [Water Solubility ]
Reacts with water. | [Sensitive ]
Air Sensitive | [InChI]
1S/C4H9.BrH.Zn/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1 | [InChIKey]
WYBHVVXVUCUWSE-UHFFFAOYSA-M | [SMILES]
CC(C)C[Zn]Br |
| Hazard Information | Back Directory | [Uses]
Isobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst. |
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