ChemicalBook--->CAS DataBase List--->1293-87-4

1293-87-4

1293-87-4 Structure

1293-87-4 Structure
IdentificationBack Directory
[Name]

1,1'-FERROCENEDICARBOXYLIC ACID
[CAS]

1293-87-4
[Synonyms]

1,1'-DICARBOXYFERROCENE
1,1′-Biscarboxylferrocene
Ferrocene, 1,1'-dicarboxy-
1,1'-FERROCENDICARBONSAEURE
Ferrocene dicarboxylic acid
1,1-Ferrocnedocarboxylic Acid
1,1-Ferrpemedocarboxylic Acid
1,1'- twocarboxyltwoferrocene
1,1'-FerrocenediCarbocylic acid
1,1'-FERROCENEDICARBOXYLIC ACID
FERROCENE-1,1'-DICARBOXYLIC ACID
BIS(CARBOXYCYCLOPENTADIENYL)IRON
1,1′-Ferrocenedicarboxylic acid 96%
1,1'-Ferrocenedicarboxylic acid ,97%
1,1'-Ferrocenedicarboxylic acid, 96+%
1,1′-Ferrocenedicarboxylic acid, >=98%
1,1'-Ferrocenedicarboxylicacid,min.96%
1,1''-FERROCENE DICARBOXYLIC ACID, MIN. 96%
Bis(carboxycyclopentadienyl) Iron 1,1'-Dicarboxyferrocene
[EINECS(EC#)]

215-068-9
[Molecular Formula]

C12H10FeO4 10*
[MDL Number]

MFCD00001423
[MOL File]

1293-87-4.mol
[Molecular Weight]

274.05
Chemical PropertiesBack Directory
[Appearance]

dark brown powder
[Melting point ]

≥300 °C(lit.)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

orange
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Insoluble
[CAS DataBase Reference]

1293-87-4
[NIST Chemistry Reference]

1,1'-Ferrocenedicarboxylic acid(1293-87-4)
Hazard InformationBack Directory
[Chemical Properties]

dark brown powder
[Uses]

Reactant for preparation of:
  • Planar chiral ferrocene-based amido-phosphine ligands as catalysts for asymmetric allylic alkylation reactions
  • Potential antitumor agents
  • Isostructural ferrocenyl coordination polymer hollow microspheres with H2 storage properties
  • Prganometallic aromatic polyesters
  • Manganese-lanthanide-ferrocene clusters
[Purification Methods]

It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

36/37/38-22
[Safety Statements ]

26-36-37/39
[WGK Germany ]

3
[HS Code ]

29319090
Spectrum DetailBack Directory
[Spectrum Detail]

1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)MS
1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)1HNMR
1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)13CNMR
1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)IR1
1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)IR2
1,1'-FERROCENEDICARBOXYLIC ACID(1293-87-4)ESR
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