| Identification | Back Directory | [Name]
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO | [CAS]
1295649-40-9 | [Synonyms]
Ru-MACHO(regR)
Ru-MACHO[R] (contains 5% Toluene at maximum)
Ru-MACHO(regR) (contains 5% Toluene at maximum)
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II)
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)aMino]rutheniuM(II), Min.98% Ru-MACHO
Carbonylchlorohydrido[bis(2-(diphenylphosphinoethyl)amino]ruthenium(II), min.98% Ru-MACHO(TM) | [Molecular Formula]
C29H30ClNOP2Ru | [MDL Number]
MFCD22377801 | [MOL File]
1295649-40-9.mol | [Molecular Weight]
608.04 |
| Chemical Properties | Back Directory | [Melting point ]
260-290 °C | [storage temp. ]
2-8°C, stored under nitrogen | [form ]
Powder | [color ]
white to yellow | [Sensitive ]
air sensitive | [InChI]
1S/C28H29NP2.CO.ClH.Ru/c1-5-13-25(14-6-1)30(26-15-7-2-8-16-26)23-21-29-22-24-31(27-17-9-3-10-18-27)28-19-11-4-12-20-28;1-2;;/h1-20,29H,21-24H2;;1H;/q;;;+1/p-1 | [InChIKey]
GQFWSAKCCNATEV-UHFFFAOYSA-M | [SMILES]
Cl[Ru].[C-]#[O+].C(CP(c1ccccc1)c2ccccc2)NCCP(c3ccccc3)c4ccccc4 | [CAS DataBase Reference]
1295649-40-9 |
| Questions And Answer | Back Directory | [Reaction]
- Highly efficient ruthenium-catalyzed used in the N-formylation of amines with hydrogen and carbon dioxide.
- Rutheniumcatalyzed hydrogen generation from glycerol and selective synthesis of lactic acid
|
| Hazard Information | Back Directory | [Uses]
<ul>
<li><strong>Dehydrogenative Intramolecular Macrolactonization:</strong> Ru-MACHO catalyst is applied in dehydrogenative intramolecular macrolactonization of dihydroxy compounds, demonstrating its efficiency in organic synthesis with potential implications for pharmaceutical synthesis (Jamdade et al., 2022).</li>
<li><strong>Acceptorless Dehydrogenation of Methanol:</strong> Employing Ru-MACHO catalyst in the acceptorless dehydrogenation of methanol to produce carbon monoxide and hydrogen, this process highlights Ru-MACHO′s capability in catalytic transformations and green chemistry applications (Kaithal et al., 2021).</li>
<li><strong>Precapture and Hydrogenation of CO2:</strong> A study on the heterogenized Ru-MACHO catalytic systems for pre-capture and hydrogenation of CO2 into methanol, underscoring the catalyst′s potential in sustainable chemical processes (Szego et al., 2023).</li>
<li><strong>Pressure-dependent Hydrogenative Depolymerization:</strong> The Ru-MACHO catalyst is used for highly selective pressure-dependent hydrogenative depolymerization of polybutylene succinate, demonstrating the catalyst′s versatility in polymer processing and chemical recycling (Johnson et al., 2024).</li>
</ul> | [reaction suitability]
core: ruthenium
reagent type: catalyst |
|
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
parabiochem
|
| Tel: |
025-83453382-8005 |
| Website: |
www.parabiochem.cn |
| Company Name: |
Rhawn Reagent
|
| Tel: |
400-400-1332688 18019345275 |
| Website: |
http://www.rhawn.cn |
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