| Identification | More | [Name]
NICKEL NITRATE | [CAS]
13138-45-9 | [Synonyms]
NICKEL ICP STANDARD, NI(NO3)2
NICKEL (II) NITRATE
NICKEL NITRATE
NI(NO3)2
nickel(2+)nitrate
nickel(ii)nitrate(1:2)
nickelbis(nitrate)
nickeldinitrate
nickelionchromatographystdsol.fluka
nickelnitrate[ni(no3)2]
nickelous
Nickelousnitrate,anhydrous
NitricAcid,Nickel(2+)Salt
nitricacid,nickel(2++)salt
nitricacid,nickel(ii)salt
Nickel ion chromatography standard solution Fluka
NICKEL ION CHROMATOGRAPHY STD SOL. FLUKA , IN NITRIC AC.
nickel standard for ic
nickel(ii) nitrate solution
Nickel(II)-nitrat | [EINECS(EC#)]
236-068-5 | [Molecular Formula]
N2NiO6 | [MDL Number]
MFCD00011139 | [Molecular Weight]
182.7 | [MOL File]
13138-45-9.mol |
| Chemical Properties | Back Directory | [Appearance]
Green, deliquescent crystals.Soluble in water, ammonium
hydroxide, and alcohol. | [Melting point ]
105-110 °C (decomp) | [vapor pressure ]
0.003Pa at 25℃ | [solubility ]
soluble in ethanol | [form ]
Liquid | [color ]
Green | [Water Solubility ]
g/100g solution H2O: 44.2 (0°C), 50.0 (25°C), 69.2 (99.5°C); solid phase, Ni(NO3)2 ·6H2O (0°C, 25°C), Ni(NO3)2 ·2H2O (99.5°C) [KRU93] | [Merck ]
13,6537 | [Uses]
Nickel plating, preparation of nickel catalysts,
manufacture of brown ceramic colors. | [CAS DataBase Reference]
13138-45-9(CAS DataBase Reference) | [EPA Substance Registry System]
Nickel(II) nitrate (13138-45-9) |
| Hazard Information | Back Directory | [Chemical Properties]
Green, deliquescent crystals.Soluble in water, ammonium
hydroxide, and alcohol. | [Chemical Properties]
Nickel nitrate is a green powder. | [General Description]
NICKEL NITRATE(13138-45-9) is a green crystalline solid. NICKEL NITRATE(13138-45-9) is soluble in water. NICKEL NITRATE(13138-45-9) is noncombustible, but NICKEL NITRATE(13138-45-9) will accelerate the burning of combustible materials. If large quantities are involved in a fire or the combustible material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Toxic oxides of nitrogen are produced in fires involving this material. NICKEL NITRATE(13138-45-9) is used in nickel plating and to make nickel catalysts for use in chemical manufacture. | [Reactivity Profile]
Green, crystalline material, toxic and carcinogenic. A powerful oxidizer, NICKEL NITRATE may cause a violent reaction with reducing materials (e.g., magnesium or aluminum powder, tin(II) chloride). Dangerous fire hazard, acts as oxygen carrier. When heated to decomposition NICKEL NITRATE emits highly toxic fumes of oxides of nitrogen [Lewis, 3rd ed., 1993, p. 915]. Complexes with tetrammine and tetrahydrazine are explosive [Bretherick, 5th ed., 1995, p. 1685]. | [Air & Water Reactions]
Soluble in water. | [Hazard]
Dangerous fire risk, strong oxidizing agent. | [Health Hazard]
Inhalation of dust causes irritation of nose and throat. Ingestion causes vomiting. Dust irritates eyes and may cause dermatitis in contact with skin. | [Potential Exposure]
Nickel nitrate is used in electroplating,
in nickel catalyst production for making other chemicals
and the manufacture of brown ceramic colors. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including
resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical
attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit.
| [Shipping]
UN2725 Nickel Nitrate, Hazard Class: 5.1;
Labels: 5.1-Oxidizer. | [Incompatibilities]
A strong oxidizer. Incompatible with
strong acids; sulfur, combustibles, organics, and other easily
oxidizable materials. Noncombustible, but it will accelerate
the burning of combustible materials. If large
quantities are involved in a fire or the combustible material
is finely divided, an explosion may result. Prolonged exposure
to fire or heat may result in an explosion. | [Waste Disposal]
Consult with environmental
regulatory agencies for guidance on acceptable disposal
practices. Generators of waste containing this contaminant
(≥100 kg/mo) must conform with EPA regulations
governing storage, transportation, treatment, and waste
disposal. | [Physical properties]
The hexahydrate forms emerald green monoclinic crystals; hygroscopic; density 2.05 g/cm3; isomorphous with corresponding cobalt salt; melts at 56.7°C; loses water on heating, decomposing to nickel oxide; very soluble in water; aqueous solution acidic; soluble in ethanol. | [Flammability and Explosibility]
Nonflammable |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R45:May cause cancer. | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN3264 | [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
III | [Safety Profile]
Confirmed human
carcinogen. Poison by intravenous route.
Experimental reproductive effects. Mutation
data reported. A powerful oxilzer. When
heated to decomposition it emits very toxic
fumes of NOx. See also NICKEL
COMPOUNDS and NITRATES. | [Hazardous Substances Data]
13138-45-9(Hazardous Substances Data) |
| Questions And Answer | Back Directory | [Uses]
Nickel nitrate is used in the preparation of nickel-impregnated catalysts. It also is used to make nickel plates in nickel-cadmium batteries. Other applications are in ceramics to produce brown colors and in preparing nickel oxide.
| [Preparation]
Nickel nitrate hexahydrate may be prepared by several methods based on the reaction of dilute nitric acid on nickel powder, nickel oxide or nickel carbonate. The reaction is exothermic and requires controlled cooling during production. The hexahydrate can be dehydrated to anhydrous salt by treatment with fuming nitric acid.
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