| Identification | Back Directory | [Name]
Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)-carboxylate) | [CAS]
131766-06-8 | [Synonyms]
Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)-carboxylate) | [Molecular Formula]
C24H40N4O8Rh2 | [MOL File]
131766-06-8.mol | [Molecular Weight]
718.42 |
| Hazard Information | Back Directory | [Uses]
Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)-carboxylate) is used as a highly enantioselective catalyst for carbenoid reactions of diazo compounds. | [Preparation]
Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)-carboxylate) is prepared from Dirhodium(II) Tetraacetate by ligand substitution with methyl 2-pyrrolidone-
5(S)-carboxylate.[1,2] | [storage]
Dirhodium(II) Tetrakis(methyl 2-pyrrolidone-5(S)-carboxylate) is air stable, weakly hygroscopic; stored in desiccator.
| [References]
1. Doyle, M. P.; Winchester, W. R.; Hoorn, J. A. A.; Lynch, V.; Simonsen, S. H.; Ghosh, R. JACS 1993, 115, 9968.
2. Doyle, M. P.; Winchester, W. R.; Protopopova, M. N.; Kazala, A. P.; Westrum, L. J. OS 1994, 73, in press. |
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