ChemicalBook--->CAS DataBase List--->131929-68-5

131929-68-5

131929-68-5 Structure

131929-68-5 Structure
IdentificationBack Directory
[Name]

Spinosyn A 17-pseudoaglycone
[CAS]

131929-68-5
[Synonyms]

Spinosyn A 17-pseudoaglycone
1H-as-Indaceno[3,2-d]oxacyclododecin-7,15-dione, 2-[(6-deoxy-2,3,4-tri-O-methyl-α-L-mannopyranosyl)oxy]-9-ethyl-2,3,3a,5a,5b,6,9,10,11,12,13,14,16a,16b-tetradecahydro-13-hydroxy-14-methyl-, (2R,3aS,5aR,5bS,9S,13S,14R,16aS,16bR)-
[Molecular Formula]

C33H50O9
[MDL Number]

MFCD33021337
[MOL File]

131929-68-5.mol
[Molecular Weight]

590.74
Chemical PropertiesBack Directory
[form ]

A solid
Hazard InformationBack Directory
[Description]

Spinosyn A 17-pseudoaglycone is a pseudoaglycone form of the macrocyclic lactone insecticide spinosyn A . Unlike spinosyn A, spinosyn A 17-pseudoaglycone is not lethal to tobacco budworm (H. virescens) neonate larvae (LC50 = >64 ppm).
[Uses]

Spinosyn A 17-pseudoaglycone is an acid degradation product produced by selective hydrolysis of the more labile forosamine saccharide in the 17-position of spinosyn A, the major component of the commercial product, Spinosad. Spinosyn A 17-pseudoaglycone is only weakly active as an insecticide as the forosamine moiety is considered essential for potent activity. Despite the importance of spinosyns as agro-chemical insecticides and more recently as animal health products, there are few published reports of the biological activity or the levels of spinosyn A 17-pseudoaglycone in animals or in the environment.
[References]

[1] T. C. SPARKS. Biological Activity of the Spinosyns, New Fermentation Derived Insect Control Agents, on Tobacco Budworm (Lepidoptera: Noctuidae) Larvae[J]. Journal of Economic Entomology, 1998, 91 1: 1277-1283. DOI: 10.1093/jee/91.6.1277
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