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133545-17-2

133545-17-2 Structure

133545-17-2 Structure
IdentificationBack Directory
[Name]

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
[CAS]

133545-17-2
[Synonyms]

SL-A101-2
)-(6,6′
97% (S)-MeO-BIPHEP
(S)-(-)-MeO-BIPHEP
-Dimethoxybiphenyl-2,2′
-diyl)bis(diphenylphosphine)
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
(S)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny
(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
(S)-(-)-2,3'-Bis(diphenylphosphino)-6-6'-dimethoxy-1,1'-biphenyl
(R)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine)
1,1'-[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine
Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(S)-MeO-BIPHEP
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (S)-MeO-BIPHEP
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(S)-MeO-BIPHEP
(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99%
(S)-(-)-MeO-BIPHEP, SL-A101-2, (S)-(-)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
[Molecular Formula]

C38H32O2P2
[MDL Number]

MFCD03095430
[MOL File]

133545-17-2.mol
[Molecular Weight]

582.61
Chemical PropertiesBack Directory
[Melting point ]

213-216 °C
[alpha ]

-101 º (C=0.3 IN TOLUENE)
[Boiling point ]

651.1±55.0 °C(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

crystal
[color ]

white
[Optical Rotation]

Consistent with structure
[BRN ]

4790083
[InChIKey]

KRJVQCZJJSUHHO-UHFFFAOYSA-N
[SMILES]

C1(C2=C(OC)C=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)=C(OC)C=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335-H303
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P403+P233-P405-P501
[WGK Germany ]

3
[F ]

8-10-23
[HS Code ]

29319090
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Chemical Properties]

White powder
[Uses]

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
Spectrum DetailBack Directory
[Spectrum Detail]

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM(133545-17-2)1HNMR
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