| Identification | Back Directory | [Name]
ACETYLTRIMETHYLSILANE | [CAS]
13411-48-8 | [Synonyms]
SKL041
ACETYLTRIMETHYLSILAN
ACETYLTRIMETHYLSILANE
Silane,acetyltrimethyl-
1-(TRIMETHYLSILYL)ETHANONE
1-TRIMETHYLSILANYL-ETHANONE
Acetyltrimethylsilane,1-(Trimethylsilyl)ethanone | [EINECS(EC#)]
220-404-2 | [Molecular Formula]
C5H12OSi | [MDL Number]
MFCD00134244 | [MOL File]
13411-48-8.mol | [Molecular Weight]
116.23 |
| Chemical Properties | Back Directory | [Melting point ]
<0°C | [Boiling point ]
113-114°C | [density ]
0.811 g/mL at 25 °C (lit.) | [refractive index ]
n20/D 1.411(lit.) | [Fp ]
48 °F | [storage temp. ]
2-8°C | [Specific Gravity]
0.811 | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [BRN ]
2071361 | [InChI]
1S/C5H12OSi/c1-5(6)7(2,3)4/h1-4H3 | [InChIKey]
REDWSDBFBCDPNI-UHFFFAOYSA-N | [SMILES]
CC(=O)[Si](C)(C)C |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
11-36/37/38 | [Safety Statements ]
16-26-36 | [RIDADR ]
UN 1993 3/PG 2 | [WGK Germany ]
3 | [F ]
8-10-21 | [TSCA ]
No | [HazardClass ]
3.1 | [PackingGroup ]
II | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Acetyltrimethylsilane can be used as a reagent in the synthesis of dihydrophenanthrenes via a C-C insertion reaction. It is also used as a source of carbanion in the synthesis of unsymmetrical biaryls by carbanion-induced ring transformation of 2H-pyran-2-ones under mild basic conditions. |
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