ChemicalBook--->CAS DataBase List--->13411-48-8

13411-48-8

13411-48-8 Structure

13411-48-8 Structure
IdentificationBack Directory
[Name]

ACETYLTRIMETHYLSILANE
[CAS]

13411-48-8
[Synonyms]

SKL041
ACETYLTRIMETHYLSILAN
ACETYLTRIMETHYLSILANE
Silane,acetyltrimethyl-
1-(TRIMETHYLSILYL)ETHANONE
1-TRIMETHYLSILANYL-ETHANONE
Acetyltrimethylsilane,1-(Trimethylsilyl)ethanone
[EINECS(EC#)]

220-404-2
[Molecular Formula]

C5H12OSi
[MDL Number]

MFCD00134244
[MOL File]

13411-48-8.mol
[Molecular Weight]

116.23
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

113-114°C
[density ]

0.811 g/mL at 25 °C (lit.)
[refractive index ]

n20/D 1.411(lit.)
[Fp ]

48 °F
[storage temp. ]

2-8°C
[Specific Gravity]

0.811
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[BRN ]

2071361
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

11-36/37/38
[Safety Statements ]

16-26-36
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[F ]

8-10-21
[TSCA ]

No
[HazardClass ]

3.1
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Acetyltrimethylsilane can be used as a reagent in the synthesis of dihydrophenanthrenes via a C-C insertion reaction. It is also used as a source of carbanion in the synthesis of unsymmetrical biaryls by carbanion-induced ring transformation of 2H-pyran-2-ones under mild basic conditions.
Spectrum DetailBack Directory
[Spectrum Detail]

ACETYLTRIMETHYLSILANE(13411-48-8)1HNMR
ACETYLTRIMETHYLSILANE(13411-48-8)IR
ACETYLTRIMETHYLSILANE(13411-48-8)Raman
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