ChemicalBook--->CAS DataBase List--->13455-01-1

13455-01-1

13455-01-1 Structure

13455-01-1 Structure
IdentificationBack Directory
[Name]

PHOSPHORUS TRIIODIDE
[CAS]

13455-01-1
[Synonyms]

AURORA KA-1079
PHOSPHORUS IODIDE
PHOSPHORUS TRIIODIDE
phosphoroustriiodide
Phosphorous-triiodide-
PHOSPHORUS(III) IODIDE
Phosphorus triiodide 99%
Phosphorus(III)iodide,98+%
Phosphorus(III) iodide, 99+%
[EINECS(EC#)]

236-647-2
[Molecular Formula]

I3P
[MDL Number]

MFCD00011442
[MOL File]

13455-01-1.mol
[Molecular Weight]

411.69
Chemical PropertiesBack Directory
[Appearance]

dark brown to black-grey crystals or granules
[Melting point ]

61 °C(lit.)
[Boiling point ]

decomposes at 227℃ [CRC10]
[density ]

4.18 g/mL at 25 °C(lit.)
[solubility ]

reacts with H2O; soluble in ethanol
[form ]

Crystals or Granules
[color ]

Dark brown to black-gray
[Water Solubility ]

decomposed by H2O; soluble alcohol, CS2 [HAW93]
[EPA Substance Registry System]

Phosphorous triiodide (13455-01-1)
Hazard InformationBack Directory
[Chemical Properties]

dark brown to black-grey crystals or granules
[Uses]

Phosphorus Triiodide is used in the structure-?property-?reactivity studies of dithiaphospholes.
[Purification Methods]

It decomposes in moist air and must be kept in a desiccator over CaCl2. It is crystallised from sulfur-free CS2; otherwise the m decreases to ca 55o. It is best to prepare it freshly. [Germann & Traxler J Am Chem Soc 49 307 1927, Klement in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 541 1963.] HARMFUL VAPOURS.
[General Description]

Phosphorus triiodide (PI3) is a trihalide of phosphorus that can be used as a deactivator and a deoxygenating agent.
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

14-34-37
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[F ]

3-10
[HazardClass ]

4.1
[PackingGroup ]

II
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