| Identification | Back Directory | [Name]
Silane, trichloroiodo- | [CAS]
13465-85-5 | [Synonyms]
iodo trichloro silane
Silane, trichloroiodo-
Silane, trichloroiodo- (6CI,7CI,8CI,9CI) | [Molecular Formula]
Cl3ISi | [MOL File]
13465-85-5.mol | [Molecular Weight]
261.35 |
| Hazard Information | Back Directory | [Physical properties]
bp 114.5 °C/760 mmHg; mp | [Uses]
Trichloroiodosilane can be used as selective ether-cleaving reagent; also cleaves acetals; mediates
reaction of aromatic aldehydes with nitriles to yield
secondary amides;aromatic aldehydes and acrylonitrile give
iminoaldehydes. | [Preparation]
It is prepared through halogen exchange by
heating SiCl4 and sodium iodide in methylene chloride–
acetonitrile or toluene–acetonitrile. It also has been prepared
by the reaction of SiCl4 and hydrogen iodide, by heating
SiHCl3 with iodine, and by heating silicon with ICl. |
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