| Identification | Back Directory | [Name]
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE | [CAS]
136705-64-1 | [Synonyms]
(R,R)-ET-DUPHOS
(R,R)-ETHYL-DUPHOS
(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE
(-)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene,97%
(-)-1,2-Bis[(2R,5R)-2,5-diethyl-1-phospholanyl]benzene, 97+%
(-)-1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene, Kanata purity
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene(r,r)-et-duphos
(2R,2'R,5R,5'R)-2,2'-5,5'-TETRAETHYL-1,1'-(O-PHENYLENE)DIPHOSPHOLANE
(2R,2'R,5R,5'R)-2,2'-5,5'-TETRAETHYL-1,1'-(1,2-PHENYLENE)DIPHOSPHOLANE
(-)-1,2-Bis((2R,5R)-2,5-diethylphospholano)benzene,98+%(R,R)-Et-DUPHOS
(-)-1,2-Bis-[(2R,5R)-2,5-diethylphospholano]benzene, 97% (R,R-Et-Duphos)
(R,R)-Ethyl-DUPHOS, (2R,2μR,5R,5μR)-2,2μ-5,5μ-Tetraethyl-1,1μ-(o-phenylene)diphospholane | [Molecular Formula]
C22H36P2 | [MDL Number]
MFCD00142335 | [MOL File]
136705-64-1.mol | [Molecular Weight]
362.47 |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless liquid or low melting solid | [alpha ]
D25 -265° (c = 1 in hexane) | [Boiling point ]
bp0.045 138-145° | [density ]
1.01 g/mL at 25 °C
| [refractive index ]
n 20/D 1.6
| [Fp ]
>230 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [Sensitive ]
Air Sensitive | [Merck ]
13,3499 | [BRN ]
4814174 | [InChI]
1S/C22H36P2/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4/h9-12,17-20H,5-8,13-16H2,1-4H3/t17-,18-,19-,20-/m1/s1 | [InChIKey]
GVVCHDNSTMEUCS-UAFMIMERSA-N | [SMILES]
CC[C@@H]1CC[C@@H](CC)P1c2ccccc2P3[C@H](CC)CC[C@H]3CC |
| Questions And Answer | Back Directory | [Reactions]
- Ligand used in rhodium catalyzed asymmetric hydrogenation of 2-methylenesuccinamic acid.
- Cobalt-catalyzed asymmetric hydrogenation.
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