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136802-85-2

136802-85-2 Structure

136802-85-2 Structure
IdentificationBack Directory
[Name]

BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
[CAS]

136802-85-2
[Synonyms]

BIS(3,5-DIMETHYL-4-METHOXYPHENYL)CHLOROPHOSPHINE
chloro-bis(4-methoxy-3,5-dimethylphenyl)phosphane
Chlorobis(3,5-dimethyl-4-methoxyphenyl)phosphine, 98+%
Bis(3,5-diMethyl-4-Methoxyphenyl)chlorophosphine,Min.98%
Phosphinous chloride, P,P-bis(4-methoxy-3,5-dimethylphenyl)-
[Molecular Formula]

C18H22ClO2P
[MDL Number]

MFCD01630810
[MOL File]

136802-85-2.mol
[Molecular Weight]

336.79
Chemical PropertiesBack Directory
[Boiling point ]

451.7±45.0 °C(Predicted)
[density ]

1.141 g/cm 3 at 25 °C
[refractive index ]

n20/D1.597
[Fp ]

>110℃
[form ]

liquid
[color ]

colorless, viscous
[Sensitive ]

Moisture Sensitive
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

34
[Safety Statements ]

26-36/37/39-43-45
[RIDADR ]

UN3265
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Reactant for:
  • Asymmetric organocatalytic electrophilic phosphination
  • Asymmetric hydroformulation using Taddol-based chiral phosphine-phosphite ligands
  • Synthesis of ferrocene-based chiral diphosphines
  • Alcoholysis of phosphane-boranes
  • Asymmetric hydrogenations of bifep-type biferrocenes
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
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