| Identification | Back Directory | [Name]
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct | [CAS]
137203-34-0 | [Synonyms]
DABAL-Me3
DABAL-trimethylaluminum
Bis(trimethylaluminum)-DABCO(R) adduct
Triethylenediaminine bis(trimethylaluminum)
1,4-diazabicyclo[2.2.2]octane,trimethylalumane
DABAL-Me3 (adduct of trimethylaluminum and DABCO)
1,4-DIAZABICYLO[2.2.2]OCTANE BIS(TRIMETHYLALUMINUM) COMPLEX
1,4-Diazabicyclo[2.2.2]Octane Bis(Trimethylaluminum) Complex
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct
Bis(trimethylaluminium)-1,4-diazabicyclo-[2.2.2]octane adduct (DABAL-Me3)
Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) | [Molecular Formula]
C12H24Al2N2 | [MDL Number]
MFCD09265160 | [MOL File]
137203-34-0.mol | [Molecular Weight]
250.3 |
| Chemical Properties | Back Directory | [Melting point ]
>250 °C | [Fp ]
23°C (73°F) | [storage temp. ]
Hygroscopic, Room Temperature, Under inert atmosphere | [solubility ]
Benzene (Slightly), DMSO (Slightly) | [form ]
Solid | [color ]
White to Off-White | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Stability:]
Hygroscopic, Moisture Sensitive, Unstable in Aqueous Solution | [InChI]
1S/C6H12N2.6CH3.2Al/c1-2-8-5-3-7(1)4-6-8;;;;;;;;/h1-6H2;6*1H3;; | [InChIKey]
WSTAITCRSVOCTK-UHFFFAOYSA-N | [SMILES]
C[Al-](C)(C)[N+]12CC[N+](CC1)(CC2)[Al-](C)(C)C |
| Hazard Information | Back Directory | [Uses]
DABAL-Me3: An Air Stable "Methyl Anion" | [Uses]
Bis(trimethylaluminum)-DABCO(R) adduct, DABAL-Me3, DABAL-trimethylaluminum, Triethylenediaminine bis(trimethylaluminum) is a non-pyrophoric alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.1 | [General Description]
Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere. |
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Sigma-Aldrich
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Energy Chemical
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http://www.energy-chemical.com |
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