| Identification | Back Directory | [Name]
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE | [CAS]
138517-66-5 | [Synonyms]
(S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>
9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC)
(11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt | [Molecular Formula]
C16H16N2 | [MDL Number]
MFCD06654768 | [MOL File]
138517-66-5.mol | [Molecular Weight]
236.312 |
| Chemical Properties | Back Directory | [Melting point ]
158 °C | [Boiling point ]
396.7±42.0 °C(Predicted) | [density ]
1.195±0.06 g/cm3(Predicted) | [refractive index ]
20 ° (C=1, MeOH) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
powder to crystal | [pka]
9.38±0.40(Predicted) | [color ]
White to Orange to Green | [BRN ]
8693351 |
| Hazard Information | Back Directory | [Uses]
(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:
- To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
- To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
- To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.
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