ChemicalBook--->CAS DataBase List--->13861-22-8

13861-22-8

13861-22-8 Structure

13861-22-8 Structure
IdentificationBack Directory
[Name]

PROPARGYL METHACRYLATE
[CAS]

13861-22-8
[Synonyms]

Ai3-37958
Einecs 237-599-5
PROPARGYL METHACRYLATE
2-Propynyl methacrylate
prop-2-ynyl methacrylate
Methacrylicacidpropargylester
2-propyn-1-yl 2-methylpropenoate
Methacrylic acid 2-propynyl ester
prop-2-ynyl 2-methylprop-2-enoate
Propargyl methacrylate, 98%, stabilized
2-Methylpropenoic acid 2-propynyl ester
2-Propenoic acid, 2-methyl-, 2-propynyl ester
2-Propenoic acid, 2-methyl-, 2-propyn-1-yl ester
Propargyl methacrylate, 98%, stab. with ca 50ppm BHT
Propargyl methacrylate, 98%, stab. with 250ppm 4-methoxyphen
Propargyl methacrylate, stabilized with 250ppm 4-methoxyphenol
Propargyl methacrylate, 98%, stab. with 250ppm 4-methoxyphenol
Methacrylic acid propargyl ester~2-Propyn-1-yl 2-methylpropenoate
Propargyl methacrylate, 98%, stab. with 200-300ppm 4-methoxyphenol
[EINECS(EC#)]

237-599-5
[Molecular Formula]

C7H8O2
[MDL Number]

MFCD00048123
[MOL File]

13861-22-8.mol
[Molecular Weight]

124.14
Chemical PropertiesBack Directory
[Boiling point ]

149-151°C
[density ]

0,986 g/cm3
[refractive index ]

1.4500
[Fp ]

48°C
[storage temp. ]

-20°C
[form ]

liquid
[color ]

colorless to pale yellow
[Water Solubility ]

Immiscible with water.
[BRN ]

906850
[InChI]

1S/C7H8O2/c1-4-5-9-7(8)6(2)3/h1H,2,5H2,3H3
[InChIKey]

PZAWASVJOPLHCJ-UHFFFAOYSA-N
[EPA Substance Registry System]

2-Propynyl methacrylate (13861-22-8)
Safety DataBack Directory
[Risk Statements ]

10-36/37/38
[Safety Statements ]

26-28
[RIDADR ]

3272
[WGK Germany ]

WGK 3
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
Hazard InformationBack Directory
[Uses]

Propargyl methacrylate is a monomer used in polymerization reactions. It is associated with its acetylene and under goes polymerization reaction through the reversible addition fragmentation chain transfer (RAFT) process using cyanoisopropyl dithiobenzoate as a reagent.
[General Description]

Propargyl methacrylate is a methacrylate-based monomer for use in the synthesis of alkyne-functionalized polymers and copolymers. The incorporation of alkynes allows for rapid post-polymerization modification through reactions, such as copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) or thiol-yne click reactions. These reactions are highly preferable for functionalization due their high efficiency and the ability to easily install the corresponding functionality (e.g., azides or thiols) onto the biomolecule or small molecule of interest.
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