ChemicalBook--->CAS DataBase List--->139092-78-7

139092-78-7

139092-78-7 Structure

139092-78-7 Structure
IdentificationBack Directory
[Name]

4,4',4''-Tris(carbazol-9-yl)-triphenylamine
[CAS]

139092-78-7
[Synonyms]

TcTa
TCATA
4,4',4''-Tris(carbaz
Tris(4-(9H-carbazol-9-yl)
Tris(4-carbazoyl-9-ylphenyl)amine
Tris[4-(carbazol-9-yl)phenyl]amine
1,3,5-Tris(carbazol-9-ylphenyl)amine
Tris(4-carbazoyl-9-ylphenyl)amine 97%
tris(4-(9H-carbazol-9-yl)phenyl)amine
4,4',4''-Tri-9-carbazolyltriphenylamine
4,4',4''-Tri(9-carbazoyl)triphenylamine
4,4',4''-TRIS(CARBAZOL-9-YL)TRIPHENYLAMINE
4,4',4"-tris(carbazol-9-yl)triphenylaMine/TCTA
TCTA,4,4',4''-Tris(carbazol-9-yl)-triphenylaMine
4-carbazol-9-yl-N,N-bis(4-carbazol-9-ylphenyl)aniline
4,4',4''-Tri-9-carbazolyltriphenylaMine (purified by subliMation)
Benzenamine,4-(9H-carbazol-9-yl)-N,N-bis[4-(9H-carbazol-9-yl)phenyl]-
[EINECS(EC#)]

1312995-182-4
[Molecular Formula]

C54H36N4
[MDL Number]

MFCD03093250
[MOL File]

139092-78-7.mol
[Molecular Weight]

740.89
Chemical PropertiesBack Directory
[Melting point ]

298~300°C
[density ]

1.23±0.1 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

THF: soluble
chloroform: soluble
dichloromethane: soluble
[form ]

powder to crystal
[pka]

-5.97±0.60(Predicted)
[color ]

White to Orange to Green
[λmax]

326nm(CH2Cl2)(lit.)
[InChIKey]

AWXGSYPUMWKTBR-UHFFFAOYSA-N
[SMILES]

C1(N(C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)C2=CC=C(N3C4=C(C=CC=C4)C4=C3C=CC=C4)C=C2)=CC=C(N2C3=C(C=CC=C3)C3=C2C=CC=C3)C=C1
[CAS DataBase Reference]

139092-78-7
[Absorption]

λmax?293?and?326 nm (THF)
[Odor]

White powder/crystals
Hazard InformationBack Directory
[Chemical Properties]

Light yellow solid
[Description]

Having three carbazole units as the pendants and triarylamine at the core,?tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
[Uses]

4,4'',4''''-Tris(carbazol-9-yl)-triphenylamine has been patented for use in the preparation of light-emitting materials for organic electroluminescent devices.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37-36
[WGK Germany ]

3
[HS Code ]

29339900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Applications]

Having three carbazole units as the pendants and triarylamine at the core, tris(4-carbazoyl-9-ylphenyl)amine (TCTA) is electron-rich. As a result, it is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells. With low electron mobility, TCTA has also been used as exciton/electron blocking layer materials because of its high lying LUMO energy level (LUMO = 2.4 eV).
TCTA is also a very popular phosphorescent host material due to its large band gap (Eg = 3.4 eV) for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).
Spectrum DetailBack Directory
[Spectrum Detail]

4,4',4''-Tris(carbazol-9-yl)-triphenylamine(139092-78-7)1HNMR
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