ChemicalBook--->CAS DataBase List--->14049-79-7

14049-79-7

14049-79-7 Structure

14049-79-7 Structure
IdentificationBack Directory
[Name]

Zinchexacyanocobaltate
[CAS]

14049-79-7
[Synonyms]

Zinc cobalticyanide
zinc(II) hexacyanocobaltate(III)
Trizinc bis[hexacyanocobaltate(3-)]
14049-79-7 Zn3.[Co(CN)6]2 Zinchexacyanocobaltate
[Molecular Formula]

Zn3.[Co(CN)6]2
[MDL Number]

MFCD32706456
[MOL File]

14049-79-7.mol
[Molecular Weight]

313.12
Chemical PropertiesBack Directory
[InChI]

InChI=1S/12CN.2Co.3Zn/c12*1-2;;;;;/q;;;;;;;;;;;;2*-3;3*+2
[InChIKey]

PRTZFTLWWSULFO-UHFFFAOYSA-N
[SMILES]

[Zn+2].[Zn+2].[Zn+2].[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[Co-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N
[EPA Substance Registry System]

Cobaltate(3-), hexakis(cyano-.kappa.C)-, zinc (2:3), (OC-6-11)- (14049-79-7)
Safety DataBack Directory
[Symbol(GHS) ]

Environment (GHS09)
GHS09
[Signal word ]

Warning
[Hazard statements ]

H410
[Precautionary statements ]

P273-P391-P501
[TSCA ]

TSCA listed
Hazard InformationBack Directory
[Definition]

Zinc hexacyanocobaltate (ZnHCCo) is a Prussian blue analog. It could be used as a new cathode material for rechargeable LIBs used in grid-scale energy storage and conversion systems via the room temperature co-precipitation process using cost-efficient precursors, which are easily upscaled. Benefiting from the concomitant surface- and diffusion-controlled Li-ion storage, a highly reversible capacity of 121.5 mAh g?1 at 1.25 C and a 96.5% Coulombic efficiency were obtained during the charge/discharge cycling test[1].
[References]

[1] Kaiqiang Zhang. “A Hybrid Energy Storage Mechanism of Zinc Hexacyanocobaltate-Based Metal–Organic Framework Endowing Stationary and High-Performance Lithium-Ion Storage.” Electronic Materials Letters 15 4 (2019): 444–453.
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