| Identification | Back Directory | [Name]
SALCOMINE | [CAS]
14167-18-1 | [Synonyms]
o’)-o
Salcomin
SALEN-CO
Nsc32965
N,N&priMe
Co(salen)
N,N′
SALCOMINE
(sp-4-2)-
CO(SALEN)2
salcomin[qr]
a13-30876[qr]
SalcoMine
salcominepowder
Salcomine powder
o,o’)-(sp-4-2)-[qr]
salicylaldehydeethylenediiminecobalt
n,n’-bis(salicylidene)ethylenediamino
Salicylaldehyde ethylenediimine cobalt
[Bis(salicylidene)ethylenediamine]cobalt
[Bis(salicylidene)ethylenediaminato]cobalt
[N,N'-Disalicylideneethylenediamine]cobalt
N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II)
n,n’-ethylenebis(salicylideneiminato)-cobal
N,N'-Ethylenebis(salicylideneiminato)cobalt
-Bis(salicylidene)ethylenediaMinocobalt(II)
The twosalicylaldehydeethylenediaMinecobalt
Ethylenebis(salicylimine) cobalt(II) salt
(N,N'-Ethylenebis(salicylideniminato))cobalt
bis(salicylaldehyde)ethylenediiminecobalt(ii)
Bis(salicylaldehyde)ethylenediimine cobalt(ii)
N,N'-Ethylenebis(salicylideniminato)cobalt(II)
Cobalt, N,N'-ethylenebis(salicylideneiminato)-
N,N'-Bis(salicylidene)ethylenediaminecobalt(Ⅱ)
N,N'-Bis(salicyliden)ethylenediaminocobalt (ii)
[N,N'-Bis(salicylidene)ethylenediaminato]cobalt
N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II)
N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)
N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINOCOBALT(II)
N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINECOBALT(II)
N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II)
n,n-ethylenebis(salicylideneiminato)cobaltii[qr]
N,N'-Bis(salicylidene)ethylenediamine cobalt salt
n,n'-disalicylidene-ethylenediamine cobalt(ii) salt
(N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
[N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)
N,N'-Bis(salicylidene)ethylenediaminocobalt(II)
n,n’-bis(salicylidene)ethylenediaminecobalt(ii)salthyd.
Ethylenbis(nitrilomethylidyn)-2,2′-diphenolato)-cobalt(II)
Salcomine: (bis(Salicylaldehyde)ethylenediimine cobalt(II))
(ethylenebis(nitrilomethylidyne)-2,2'-diphenolato)cobalt(II)
((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal
SALCOMINE [=N,N''-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)]
Cobalt, ((alpha,alpha'-(ethylenedinitrilo)di-o-cresolato)(2-))-
SALCOMINE [=N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(2)] 95+%
Salcomine, N,N'-Disalicylidene-ethylenediamine cobalt(II) salt
cobalt,((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-[qr]
[2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II)
2,2'-((1Z,3Z)-2,3-Diaminobuta-1,3-diene-1,4-diyl)diphenol, cobalt salt
((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal
cobalt,((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n
cobalt,[[2,2’-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-n,n’,
Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-
Cobalt, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine, N,Nμ-Disalicylidene-ethylenediamine cobalt(II) salt
N,N'-Bis(salicylidene)ethylenediiminocobalt(II)
N,N'-Disalicylalethylenediamine Cobalt(II)
N,N'-Ethylenebis(salicylideneiminato)cobalt(II) | [EINECS(EC#)]
238-012-5 | [Molecular Formula]
C16H14CoN2O2 | [MDL Number]
MFCD00000009 | [MOL File]
14167-18-1.mol | [Molecular Weight]
325.23 |
| Chemical Properties | Back Directory | [Appearance]
black crystalline powder | [Melting point ]
>300 °C | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
Orange to Amber to Dark red | [Stability:]
Stable. Incompatible with strong acids, strong oxidizing agents. | [Water Solubility ]
Insoluble in water. Soluble in benzene, chloroform, and pyridine. | [InChI]
InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+; | [InChIKey]
NPAQSKHBTMUERN-OYJDLGDISA-L | [SMILES]
C12=CC=CC=C1C=NCCN=CC1=CC=CC=C1O[Co]O2 |t:7,11| | [EPA Substance Registry System]
Salcomine (14167-18-1) |
| Hazard Information | Back Directory | [Chemical Properties]
black crystalline powder | [General Description]
A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier. | [Reactivity Profile]
SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides. | [Uses]
Salcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts. | [reaction suitability]
core: cobalt
reagent type: catalyst | [Purification Methods]
The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.] |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
2
| [RTECS ]
GG0590000
| [F ]
10 | [TSCA ]
Yes | [HS Code ]
29349990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Hazardous Substances Data]
14167-18-1(Hazardous Substances Data) | [Toxicity]
mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974, |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Maya High Purity Chemicals
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Credit-Chem Co., Ltd.
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