ChemicalBook--->CAS DataBase List--->14172-90-8

14172-90-8

14172-90-8 Structure

14172-90-8 Structure
IdentificationBack Directory
[Name]

COBALT TPP
[CAS]

14172-90-8
[Synonyms]

COBALT TPP
RARECHEM AS SA 0002
PROTOPORPHYRIN IX CO (II)
COBALT TETRAPHENYLPORPHINE
(Tetraphenylporphinato)cobalt
TETRAPHENYLPORPHYRIN COBALT II
Co(II) meso-Tetraphenylporphine
Cobalt(II) Tetraphenylporphyrin
Cobalt meso-tetraphenylporphyrin
Cobalt(2+) tetraphenylporphinate
COBALT (II) MESO-TETRAPHENYLPORPHINE
Tetraphenylporphine Cobalt Complex
Cobaltmesotetraphenylporphinerustcoloredxtl
MESO-TETRAPHENYLPORPHYRIN COBALT(II) COMPLEX
5,10,15,20-TETRAPHENYLPORPHYRINATO COBALT(II)
meso-Tetraphenylporphine Cobalt(II) Complex
5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt
Cobalt, [5,10,15,20-tetraphenylporphinato(2-)]-
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE COBALT(II)
5,10,15,20-TETRAPHENYL-21H,23H-PORPHYRIN COBALT(II)
Cobalt(II) alpha,beta,gamma,delta-tetraphenylporphine
alpha,beta,gamma,delta-Tetraphenylporphinatocobalt(II)
Co(II) meso-Tetraphenylporphine (contains 1-3% chlorin)
21H,23H-Porphine, 5,10,15,20-tetraphenyl-, cobalt complex
5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE COBALT(II), SYNTHETIC
5,10,15,20-Tetraphenyl-21H,23H-porphine cobalt(II) Dye content 85 %
[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]cobalt
Cobalt, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N(21)-,N(22)-,N(23)-,N(24)-]-, (SP-4-1)-
Cobalt,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23),N24]-(SP-4-1)-
[EINECS(EC#)]

238-018-8
[Molecular Formula]

C44H28CoN4
[MDL Number]

MFCD00010725
[MOL File]

14172-90-8.mol
[Molecular Weight]

671.65
Chemical PropertiesBack Directory
[Appearance]

brown crystals or powder
[Melting point ]

>300 °C (dec.)
[density ]

1.20 g/cm3
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

crystal
[color ]

rust colored
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[λmax]

528nm(CH2Cl2)(lit.)
[InChIKey]

LSZLYWSRWXFMOI-DAJBKUBHSA-N
[SMILES]

N12[Co]N3C4C=CC3=C(C3C=CC(N=3)=C(C3=CC=CC=C3)C1=CC=C2C(C1=CC=CC=C1)=C1C=CC(C=4C2=CC=CC=C2)=N1)C1=CC=CC=C1 |c:7,14,41,t:36|
[CAS DataBase Reference]

14172-90-8
Hazard InformationBack Directory
[Chemical Properties]

brown crystals or powder
[Uses]

Co(II) meso-Tetraphenylporphine is used in the decomposition of substituted cycloheptatriene endoperoxides.
[Purification Methods]

It yields brown crystals from Et2O or CHCl3/MeOH (cf iron chloride complex). It crystallises on extraction (Soxhlet) with *C6H6. It is soluble in most organic solvents except MeOH and pet ether. [UV, IR: Rothemund & Manott J Am Chem Soc 70 1808 1948, Thomas & Martell J Am Chem Soc 81 5111 1959.]
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)
GHS08
[Signal word ]

Warning
[Hazard statements ]

H351
[Precautionary statements ]

P201-P202-P281-P308+P313-P405-P501
[WGK Germany ]

3
[HS Code ]

29339900
Spectrum DetailBack Directory
[Spectrum Detail]

COBALT TPP(14172-90-8)1HNMR
COBALT TPP(14172-90-8)IR
COBALT TPP(14172-90-8)ESR
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