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14172-92-0

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14172-92-0 Structure

14172-92-0 Structure

Identification	Back Directory
[Name] 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)
[CAS] 14172-92-0
[Synonyms] NICKEL TPP RARECHEM AS SA 0006 PROTOPORPHYRIN IX NI(II) Nickel tetraphenylporphine Nickel tetraphenylporphyrin NI(II) MESO-TETRAPHENYLPORPHINE NICKEL MESO-TETRAPHENYLPORPHINE Nickel(II) tetraphenylphorphyrin Nickel MESO-TETRAPHENYLPORPHYRIN NICKEL(II)MESO-TETRAPHENYLPORPHINE Tetraphenylporphine nickel complex 5,10,15,20-TETRAPHENYLPORPHYRIN NI(II) [meso-Tetraphenylporphinato(2-)]nickel Nickel(II) 5,10,15,20-tetraphenylporphine [5,10,15,20-Tetraphenylporphinato(2-)]nickel Ni(II) meso-Tetraphenylporphine (chlorin free) 5,10,15,20-Tetraphenyl-21H,23H-porphine nickel Nickel, [5,10,15,20-tetraphenylporphinato(2-)]- 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II) 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, nickel complex 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II), SYNTHETIC 5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II),Nickel TPP 5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II), synthetic 500MG 5,10,15,20-Tetraphenyl-21H,23H-porphine nickel(II) dye content >=95 % Nickel, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N21,N22,N23,N24]-, (SP-4-1)- ACetic acid, 2,2',2'',2'''-[21H,23H-porphine-5,10,15,20-tetrayltetrakis(4,1-phenyleneoxy)]tetrakis- Nickel,[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-N²¹,N²²,N²³,N²⁴]-(SP-4-1)-
[Molecular Formula] C44H28N4Ni
[MDL Number] MFCD00010727
[MOL File] 14172-92-0.mol
[Molecular Weight] 671.41

Chemical Properties	Back Directory
[Appearance] dark purple crystalline powder or crystals
[Melting point ] >300 °C
[storage temp. ] 2-8°C, protect from light, stored under nitrogen
[form ] crystal
[color ] purple
[Water Solubility ] Insoluble in H2O; soluble in CHCl3; slightly soluble in ether, benzene, hexane, and methanol.
[λmax] 525 nm (2nd)
[InChIKey] CXIRWLOIAQYBLZ-DAJBKUBHSA-N
[SMILES] N12[Ni]N3C4C=CC3=C(C3C=CC(N=3)=C(C3=CC=CC=C3)C1=CC=C2C(C1=CC=CC=C1)=C1C=CC(C=4C2=CC=CC=C2)=N1)C1=CC=CC=C1 \|c:7,14,41,t:36\|

Hazard Information	Back Directory
[Chemical Properties] dark purple crystalline powder or crystals
[Uses] Nickel(II) Tetraphenylporphyrinate is an electron transfer agent and catalyst for aryl halogen exchange reactions. It could be used in cyclizations of saturated ο-iodo ketones and hydrogenation of alkenes.
[reaction suitability] reagent type: catalyst core: nickel
[Purification Methods] Purify it by chromatography on neutral (Grade I) alumina, followed by recrystallisation from CH2Cl2/MeOH [Yamashita J Phys Chem 91 3055 1987]. [Beilstein 26 III/IV 1960.]
[Precautions] Stable in air and water. Some nickel compounds are known carcinogens, so standard safety precautions apply.

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H302+H312+H332
[Precautionary statements ] P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
[Hazard Codes ] Xn
[Risk Statements ] 20/21/22
[Safety Statements ] 37/39-26-36
[WGK Germany ] 3
[HS Code ] 29310099
[Storage Class] 11 - Combustible Solids
[Hazard Classifications] Acute Tox. 4 Dermal Acute Tox. 4 Inhalation Acute Tox. 4 Oral

Spectrum Detail	Back Directory
[Spectrum Detail] 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)MS 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)IR1 5,10,15,20-TETRAPHENYL-21H,23H-PORPHINE NICKEL(II)(14172-92-0)IR2

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