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142214-04-8

142214-04-8 Structure

142214-04-8 Structure
IdentificationBack Directory
[Name]

Rhodiumtriphenylacetate
[CAS]

142214-04-8
[Synonyms]

Rh2(TPA)4
oromethane Adduct
Rh2(triphenylacetate)4
DichloroMethane Adduct
Rhodiumtriphenylacetate
acetato)dirhodium(II) DichL
Rhodium(II)triphenylacetate dimer
Rhodium triphenyl acetate[Rh2(TPA)4
Tetrakis(triphenylacetato)dirhodiuM(II) 
Rhodium(II) triphenylacetate dimer, dichloromethane adduct
Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct
Rhodium(II) Bis(triphenylacetate) Dimer Dichloromethane Adduct
Dirhodium(II) Tetrakis(triphenylacetate) Dichloromethane Adduct
Rhodium(II) triphenylacetate dimer as complex with dichloromethane
Dirhodium(II) Tetrakis(triphenylacetate) Rhodium(II) Bis(triphenylacetate) Dimer
[EINECS(EC#)]

200-838-9
[Molecular Formula]

C60H45O6Rh
[MDL Number]

MFCD00191694
[MOL File]

142214-04-8.mol
[Molecular Weight]

964.901
Chemical PropertiesBack Directory
[Melting point ]

260-263°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder to crystal
[color ]

Green to Dark green
Safety DataBack Directory
[Symbol(GHS) ]


GHS08
[Signal word ]

Warning
[Hazard statements ]

H351
[Precautionary statements ]

P201-P202-P280-P308+P313-P405-P501
[Hazard Codes ]

Xn
[Risk Statements ]

40
[Safety Statements ]

23-24/25-36/37
[WGK Germany ]

2
[HS Code ]

2931.90.6000
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Amination of allene carbamates
  • Allene aziridination to stereoselectively prepare cyclic cabamates
  • C-H bond nitrene insertion
  • Enantioselective cyclopropanation
  • Preparation of cyclic oxonium ylides
[reaction suitability]

core: rhodium
reagent type: catalyst
reaction type: C-H Activation
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