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142374-19-4

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142374-19-4 Structure

142374-19-4 Structure
IdentificationBack Directory
[Name]

N-BOC-4-PIPERIDINEACETALDEHYDE
[CAS]

142374-19-4
[Synonyms]

tert-Butyl 4-(2-oxoethyl)
n-boc-4-piperidineacetaldehyde
1-Boc-4-(2-oxo-ethyl)piperidine
1-PIPERIDINE CARBOXYLIC ACID, 4-(2
N-Boc-4-piperidineacetaldehyde 97%
2-(N-BOC-4-piperidinyl)acetaldehyde
tert-butyl 4-(2-oxoethyl)piperidin-1-carboxylate
tert-butyl 4-(2-oxoethyl)piperidine-1-carboxylate
1-PIPERIDINE CARBOXYLIC ACID, 4-(2-OXOETHYL)-1,1-D
1-(tert-butyloxycarbonyl)-piperidine-4-acetaldehyde
tert-Butyl 4-(formylmethyl)piperidine-1-carboxylate
1-Piperidinecarboxylic acid, 4-(2-oxoethyl)-, 1,1-diMethylethyl ester
N-Boc-4-piperidineacetaldehyde/tert-butyl 4-(2-oxoethyl)piperidine-1-carboxylate
[Molecular Formula]

C12H21NO3
[MDL Number]

MFCD03425258
[MOL File]

142374-19-4.mol
[Molecular Weight]

227.3
Chemical PropertiesBack Directory
[Melting point ]

38-42 °C
[Boiling point ]

318.1±15.0 °C(Predicted)
[density ]

1.035±0.06 g/cm3(Predicted)
[Fp ]

>110℃
[storage temp. ]

Inert atmosphere,Store in freezer, under -20°C
[form ]

solid
[pka]

-1.62±0.40(Predicted)
[Appearance]

Colorless to light yellow <38°C Solid,>42°C Liquid
[Major Application]

peptide synthesis
[InChI]

InChI=1S/C12H21NO3/c1-12(2,3)16-11(15)13-7-4-10(5-8-13)6-9-14/h9-10H,4-8H2,1-3H3
[InChIKey]

PSRHRFNKESVOEL-UHFFFAOYSA-N
[SMILES]

N1(C(OC(C)(C)C)=O)CCC(CC=O)CC1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

N-Boc-4-piperidineacetaldehyde is used in the preparation of benzofuran-2-carboxylic acid based Pim-1 inhibitors.
[Uses]

Reactant for synthesis of:
  • Pim-1 inhibitors
  • Selective GPR119 agonists for type II diabetes


Reactant for:
  • α-arylation of aldehydes
  • Enantioselective α-benzylation of aldehydes via photoredox organocatalysis
  • Enantioselective α?triflouromethylation of aldehydes
Spectrum DetailBack Directory
[Spectrum Detail]

N-BOC-4-PIPERIDINEACETALDEHYDE(142374-19-4)1HNMR
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