| Identification | Back Directory | [Name]
MN(TMHD)3 | [CAS]
14324-99-3 | [Synonyms]
Mn(dpm)3
MN(TMHD)3
Shenvi Hydrogenation Catalyst
Tris(dipivaloylmethanato)manganese
Tris(tetramethylheptanedionato)manganese
2,2,6,6-TetraMethyl-3,5-heptanedionate(III)Manganese
MANGANESE(lll) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese
Manganese tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
Tris(2,2,6,6tetramethyl-3,5-heptanedionato)manganese(Ⅲ)
Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(II)
Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III)
Manganese(III)tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III)
Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) manganese (III)
Tris-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O'')-manganese
tris(((Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-yl)oxy)manganese
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese (III), (Mn(TMHD)3)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) 99% [MN(TMHD)3] | [Molecular Formula]
C33H57MnO6 | [MDL Number]
MFCD00269825 | [MOL File]
14324-99-3.mol | [Molecular Weight]
604.74 |
| Chemical Properties | Back Directory | [Melting point ]
165°C | [Boiling point ]
255°C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
crystal | [color ]
black | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [InChI]
1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-; | [InChIKey]
ORZPLLPBZHORSD-LWTKGLMZSA-K | [SMILES]
CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C |
| Hazard Information | Back Directory | [Uses]
Catalyst for:
- Intramolecular Diels-Alder reactions
- Single electron donor for excess electron transfer studies in DNA
- Enantioselective synthesis
- Borylation reactions
- Hydrohydrazination and hydroazidation
- Oxidative carbonylation of phenol
| [reaction suitability]
core: manganese
reagent type: catalyst | [Synthesis]
To a mixture of manganese (II) sulfate monohydrate (1.5 g, 9 mmol, 1.0 eq) and 2,2,6,6-tetramethyl-3,5-heptanedione (5.0 g, , 27 mmol, 4.0 eq) in water (30 mL) and methanol (6 mL) was added dropwise a concentrated ammonia solution (12 ) at room temperatur |
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