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14324-99-3

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14324-99-3 Structure

14324-99-3 Structure
IdentificationBack Directory
[Name]

MN(TMHD)3
[CAS]

14324-99-3
[Synonyms]

Mn(dpm)3
MN(TMHD)3
Shenvi Hydrogenation Catalyst
Tris(dipivaloylmethanato)manganese
Tris(tetramethylheptanedionato)manganese
2,2,6,6-TetraMethyl-3,5-heptanedionate(III)Manganese
MANGANESE(lll) 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese
Manganese tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
Tris(2,2,6,6tetramethyl-3,5-heptanedionato)manganese(Ⅲ)
Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(II)
Bis-(2,2,6,6-tetramethyl-3,5-heptandionato)manganese(III)
Manganese(III)tris(2,2,6,6-tetramethyl-3,5-heptanedionate)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III)
Tris(2,2,6,6-tetramethyl-3,5-heptanedionate) manganese (III)
Tris-(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O'')-manganese
tris(((Z)-2,2,6,6-tetramethyl-5-oxohept-3-en-3-yl)oxy)manganese
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese (III), (Mn(TMHD)3)
TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)MANGANESE (III) 99% [MN(TMHD)3]
[Molecular Formula]

C33H57MnO6
[MDL Number]

MFCD00269825
[MOL File]

14324-99-3.mol
[Molecular Weight]

604.74
Chemical PropertiesBack Directory
[Melting point ]

165°C
[Boiling point ]

255°C
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

crystal
[color ]

black
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[InChI]

1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
[InChIKey]

ORZPLLPBZHORSD-LWTKGLMZSA-K
[SMILES]

CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39-36/37
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol
[reaction suitability]

core: manganese
reagent type: catalyst
[Synthesis]

To a mixture of manganese (II) sulfate monohydrate (1.5 g, 9 mmol, 1.0 eq) and 2,2,6,6-tetramethyl-3,5-heptanedione (5.0 g, , 27 mmol, 4.0 eq) in water (30 mL) and methanol (6 mL) was added dropwise a concentrated ammonia solution (12 ) at room temperatur
Spectrum DetailBack Directory
[Spectrum Detail]

MN(TMHD)3(14324-99-3)1HNMR
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