| Identification | Back Directory | [Name]
5-Bromo-2-hydroxyacetophenone | [CAS]
1450-75-5 | [Synonyms]
-Bromo-2’
AKOS BBS-00006622
5-BroMo-2-hydroxyace
2-ACETYL-4-BROMOPHENOL
5-Methyl-6-Hydroxysalicylate
5-BROMO-2-HYDROXYACETOPHENONE
5'-BROMO-2'-HYDROXYACETOPHENONE
2’-hydroxy-5’-bromoacetophenone
5’-bromo-2’-hydroxy-acetophenon
1-(5-bromo-2-hydroxyphenyl)-ethanon
1-(5-BROMO-2-HYDROXYPHENYL)ETHANONE
5'-Bromo-2'-hydroxyacetophenone,98%
5'-BroMo-2'-hydroxyacetophenone, 97+%
1-(3-broMophenyl)-2-hydroxyethan-1-one
17459
5''-BROMO-2''- HYDROXYACETOPHENONE
5'-bromo-2'-hydroxyacetophenone ,1-(5-bromo-2-hydroxy)ethanone
1-(5-Bromo-2-hydroxyphenyl)ethan-1-one, 2-Acetyl-4-bromophenol
5-Bromo-2-Hydroxy Acetophenone 5'-Bromo-2'-Hydroxy Acetophenone
5'-BroMo-2'-hydroxyacetophenone (2'-hydroxy-5'-broMoacetophenone) | [EINECS(EC#)]
604-457-2 | [Molecular Formula]
C8H7BrO2 | [MDL Number]
MFCD00191850 | [MOL File]
1450-75-5.mol | [Molecular Weight]
215.04 |
| Chemical Properties | Back Directory | [Appearance]
White to pale yellow crystalline powder | [Melting point ]
58-61 °C(lit.)
| [Boiling point ]
135-143 °C(Press: 16 Torr) | [density ]
1.586±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Soluble in Chloroform | [form ]
Solid | [pka]
9.59±0.18(Predicted) | [color ]
White to pale yellow | [InChI]
InChI=1S/C8H7BrO2/c1-5(10)7-4-6(9)2-3-8(7)11/h2-4,11H,1H3 | [InChIKey]
HQCCNFFIOWYINW-UHFFFAOYSA-N | [SMILES]
C(=O)(C1=CC(Br)=CC=C1O)C | [LogP]
3.110 (est) |
| Hazard Information | Back Directory | [Chemical Properties]
White to pale yellow crystalline powder | [Uses]
5?-Bromo-2?-hydroxyacetophenone (5-Bromo-2-hydroxyacetophenone) may be used in ligand in the preparation of tetrahedral metallocene complexes containing vanadium(IV), synthesis of {2?-[1-(5-bromo-2-oxidophenyl) ethylidene] benzohydrazidato (2-)} tris(pyridine) nickel(II)] pyridine solvate, synthesis of N?-[1-(5-bromo-2-hydroxyphenyl)ethylidene]-3,4,5-trihydroxybenzohydrazide dimethyl sulfoxide solvate trihydrate, preparation of 6-bromochromen-4-one. | [Preparation]
Preparation by Fries rearrangement of 4-bromophenyl acetate with aluminium chloride without solvent between 110° and 160° (84–91%). |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [WGK Germany ]
3
| [RTECS ]
KM5556350
| [Hazard Note ]
Irritant | [HazardClass ]
IRRITANT | [HS Code ]
29147000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Toxicity]
mouse,LD50,intraperitoneal,> 1gm/kg (1000mg/kg),Indian Journal of Chemistry, Section B: Organic Chemistry, Including Medicinal Chemistry. Vol. 20, Pg. 480, 1981. |
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J & K SCIENTIFIC LTD.
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Energy Chemical
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Shanghai Ennopharm Co., Ltd.
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