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14666-78-5

14666-78-5 Structure

14666-78-5 Structure
IdentificationBack Directory
[Name]

Diethyl peroxydicarbonate
[CAS]

14666-78-5
[Synonyms]

Diethyl peroxydiformate
Diethyl peroxydicarbonate
Bis(ethoxyformyl) peroxide
Bis(ethoxycarbonyl) peroxide
Peroxybis(formic acid ethyl) ester
Peroxydicarbonic acid diethyl ester
diethyl peroxydicarbonate, <= 27% in solution
ethoxycarbonyloxy ethyl carbonate[in solution, content ≤27%]
[EINECS(EC#)]

238-707-3
[Molecular Formula]

C6H10O6
[MOL File]

14666-78-5.mol
[Molecular Weight]

178.14
Chemical PropertiesBack Directory
[Boiling point ]

230.35°C (rough estimate)
[density ]

1.3253 (rough estimate)
[refractive index ]

1.5860 (estimate)
[EPA Substance Registry System]

Peroxydicarbonic acid, diethyl ester (14666-78-5)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07,GHS02
[Signal word ]

Danger
[Hazard statements ]

H226-H242-H315-H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501
[RIDADR ]

3115
[HazardClass ]

5.2
[PackingGroup ]

II
[Safety Profile]

The impure material is a powerful explosive extremely sensitive to heat or impact. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES.
Hazard InformationBack Directory
[General Description]

Diethyl peroxydicarbonate is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. Diethyl peroxydicarbonate is generally stored or transported in a solvent slurry, water, alcohol, etc.
[Reactivity Profile]

Diethyl peroxydicarbonate decomposes violently or explosively at temperatures 0-10°C owing to self-accelerating exothermic decomposition. Several explosions were due to shock, heat or friction. Amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry.
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