147702-13-4

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147702-13-4 Structure

Identification	Back Directory
[Name] (S)-VANOL
[CAS] 147702-13-4
[Synonyms] (S)-VANOL (R)-VANOL (R)-VANOL 97% (R)-VANOL,99%e.e. (R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL (S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL) (2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL (2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL (2R)-(+)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (R)-VANOL (2R)-(+)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(R)-VANOL (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthalol, (R)-3,3μ-Diphenyl-2,2μ-bi-1-naphthol
[Molecular Formula] C32H22O2
[MDL Number] MFCD08459338
[MOL File] 147702-13-4.mol
[Molecular Weight] 438.52

Chemical Properties	Back Directory
[Melting point ] 200-204 °C
[alpha ] +362° (c 1.0, THF)
[Boiling point ] 580.1±50.0 °C(Predicted)
[density ] 1.251±0.06 g/cm3(Predicted)
[storage temp. ] 2-8°C
[form ] Powder
[pka] 7.71±0.50(Predicted)
[color ] white to pale yellow
[Optical Rotation] [α]20/D +310°, c = 1 in chloroform
[CAS DataBase Reference] 147702-13-4

Safety Data	Back Directory
[Symbol(GHS) ] GHS05,GHS07
[Signal word ] Danger
[Hazard statements ] H315-H318-H335-H413
[Precautionary statements ] P273-P280-P302+P352-P305+P351+P338+P310
[Hazard Codes ] Xi
[Risk Statements ] 37/38-41
[Safety Statements ] 26-39
[WGK Germany ] 3

Questions And Answer	Back Directory
[Reaction] Chiral ligand used in catalytic asymmetric aziridination. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes.

Hazard Information	Back Directory
[Uses] VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

Spectrum Detail	Back Directory
[Spectrum Detail] (S)-VANOL(147702-13-4)¹HNMR

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