ChemicalBook--->CAS DataBase List--->147702-14-5

147702-14-5

147702-14-5 Structure

147702-14-5 Structure
IdentificationBack Directory
[Name]

(S)-VANOL
[CAS]

147702-14-5
[Synonyms]

(S)-VANOL
(R)-VANOL
(S)-VANOL 97%
(S)-VANOL,99%e.e.
(R)-3,3'-DIPHENYL-2,2'-BI-1-NAPHTHALOL
(S)-3,3'-DIPHENYL-2,2'-BI(1-NAPHTHALOL)
(2R)-(+)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
(2S)-(-)-3,3'-DIPHENYL-[2,2'-BINAPHTHALENE]-1,1'-DIOL
(2S)-(-)-3,3''-DIPHENYL-[2,2''-BINAPHTHALENE]-1,1''-DIOL (S)-VANOL
(2S)-(-)-3,3'-Diphenyl-[2,2'-binaphthalene]-1,1'-diol,min.98%(S)-VANOL
(S)-3,3μ-Diphenyl-2,2μ-bi(1-naphthalol), (S)-3,3μ-Diphenyl-2,2μ-bi-(1-naphthol)
[Molecular Formula]

C32H22O2
[MDL Number]

MFCD08459338
[MOL File]

147702-14-5.mol
[Molecular Weight]

438.52
Chemical PropertiesBack Directory
[Melting point ]

199-203 °C
[alpha ]

-372.3° (c 1.0, THF)
[Boiling point ]

580.1±50.0 °C(Predicted)
[density ]

1.251±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[form ]

Powder
[pka]

7.71±0.50(Predicted)
[color ]

white to pale yellow
[Optical Rotation]

[α]20/D -314°, c = 1 in chloroform
[InChI]

1S/C32H22O2/c33-31-25-17-9-7-15-23(25)19-27(21-11-3-1-4-12-21)29(31)30-28(22-13-5-2-6-14-22)20-24-16-8-10-18-26(24)32(30)34/h1-20,33-34H
[InChIKey]

NDTDVKKGYBULHF-UHFFFAOYSA-N
[SMILES]

Oc1c(c(cc2ccccc12)-c3ccccc3)-c4c(O)c5ccccc5cc4-c6ccccc6
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H315-H318-H335-H413
[Precautionary statements ]

P273-P280-P302+P352-P305+P351+P338+P310
[Hazard Codes ]

Xi
[Risk Statements ]

37/38-41
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 4
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Questions And AnswerBack Directory
[Reactions]

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric aminoallylation of aldehydes.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-14-5
Hazard InformationBack Directory
[Uses]

VANOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-VANOL(147702-14-5)1HNMR
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