ChemicalBook--->CAS DataBase List--->147702-15-6

147702-15-6

147702-15-6 Structure

147702-15-6 Structure
IdentificationBack Directory
[Name]

(R)-VAPOL
[CAS]

147702-15-6
[Synonyms]

(R)-VAPOL
(S)-VAPOL
(S)-VAPOL 97%
(S)-VAPOL,99%e.e.
(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL)
(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL)
(3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
(3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT
(3S)-(+)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (S)-VAPOL
(3S)-(+)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(S)-VAPOL
[EINECS(EC#)]

200-838-9
[Molecular Formula]

C41H28Cl2O2
[MDL Number]

MFCD08459339
[MOL File]

147702-15-6.mol
[Molecular Weight]

623.57
Chemical PropertiesBack Directory
[Melting point ]

185-191 °C
[alpha ]

+125.0° (c 1.0, THF)
[Boiling point ]

712.2±60.0 °C(Predicted)
[density ]

1.286±0.06 g/cm3(Predicted)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[form ]

Powder
[pka]

8.37±0.30(Predicted)
[color ]

white to pale yellow
[Optical Rotation]

[α]20/D 128°, c = 1 in chloroform
[InChIKey]

FXFOHEGGSYVOKR-UHFFFAOYSA-N
[CAS DataBase Reference]

147702-15-6
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H351
[Precautionary statements ]

P201-P302+P352-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

37/38-40-41
[Safety Statements ]

26-36/37/39-36/37-24/25-23
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reactions]

  1. Chiral ligand in asymmetric autoinduction of Diels-Alder reactions.
  2. Chiral ligand used in catalytic asymmetric aziridination.
  3. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  4. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-15-6
Hazard InformationBack Directory
[Uses]

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.
Spectrum DetailBack Directory
[Spectrum Detail]

(R)-VAPOL(147702-15-6)1HNMR
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