| Identification | Back Directory | [Name]
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE | [CAS]
148461-14-7 | [Synonyms]
Diphenylphosphinophenylmethylethyldihydrooxazole
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline
(-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
(-)(4S)-2-[2-(Diphenylphosphino)phenyl]-4-(2-propyl)oxazoline 97%
(S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
(4S)-2-(2-(Diphenylphosphino)phenyl)-4-isopropyl-4,5-dihydrooxazole
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE
[2-[(4S)-4-isopropyl-4,5-Dihydrooxazol-2-yl]phenyl]-diphenyl-phosphane
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4S)-(-)-2-(2-Diphenylphosphanyl-phenyl)-4-isopropyl-4,5-dihydro-oxazole
(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-Oxazole
(S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
(S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
(4S)-(-)-4,5-Dihydro-2-[2'-(diphenylphosphino)phenyl]-4-isopropyloxazole,98%
Oxazole,2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-4-(1-Methylethyl)-, (4S)-
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline >=97.0% (CHN)
(S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-(1-methylethyl)-4,5-dihydrooxazole,98%
(4S)-2-[2-(Diphenylphosphino)phenyl]-4,5-dihydro-4-(1-methylethyl)oxazole,99%e.e. | [Molecular Formula]
C24H24NOP | [MDL Number]
MFCD03427599 | [MOL File]
148461-14-7.mol | [Molecular Weight]
373.43 |
| Chemical Properties | Back Directory | [Appearance]
White crystalline powder | [Melting point ]
85-90 °C
| [alpha ]
-44° (c 1.4, CHCl3) | [Boiling point ]
492.7±28.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
Powder | [pka]
4.31±0.70(Predicted) | [color ]
white | [Optical Rotation]
[α]20/D 48±3°, c = 1% in chloroform | [Sensitive ]
air sensitive | [BRN ]
5879302 | [InChI]
1S/C24H24NOP/c1-18(2)22-17-26-24(25-22)21-15-9-10-16-23(21)27(19-11-5-3-6-12-19)20-13-7-4-8-14-20/h3-16,18,22H,17H2,1-2H3/t22-/m1/s1 | [InChIKey]
OUQSAXROROGQEE-JOCHJYFZSA-N | [SMILES]
CC(C)[C@H]1COC(=N1)c2ccccc2P(c3ccccc3)c4ccccc4 |
| Hazard Information | Back Directory | [Chemical Properties]
White crystalline powder | [Uses]
Used as a phosphine ligand for a variety of organic synthesis reactions, including hydrogenation, hydroformylation, and cross-coupling reactions. |
| Questions and Answers (Q&A) | Back Directory | [Reactions]
- Chiral ligand used in the asymmetric reduction of highly substituted olefins.
- Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
- Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
- Decarboxylative allylic alkylation.
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
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